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氯氟吡氧乙酸

氯氟吡氧乙酸用途

Fluroxypyr 是一种生长素除草剂,用于控制一年生或多年生杂草。Fluroxypyr 会导致生长素过量或内源性生长素浓度过高,从而导致生长素稳态失衡以及与组织中其他激素的相互作用。

氯氟吡氧乙酸名称

[ CAS 号 ]:
69377-81-7

[ 中文名 ]:
氯氟吡氧乙酸

[ 英文名 ]:
Fluroxypyr

[中文别名 ]:

[英文别名 ]:

氯氟吡氧乙酸生物活性

[ 描述 ]:

Fluroxypyr 是一种生长素除草剂,用于控制一年生或多年生杂草。Fluroxypyr 会导致生长素过量或内源性生长素浓度过高,从而导致生长素稳态失衡以及与组织中其他激素的相互作用。

[ 相关类别 ]:

研究领域 >> 其他
信号通路 >> 其他 >> 其他

[参考文献]

[1]. Meijun Guo, et al. Comprehensive evaluation of fluroxypyr herbicide on physiological parameters of spring hybrid millet. PeerJ. 2019 Sep 26:7:e7794.  

氯氟吡氧乙酸物理化学性质

[ 密度 ]:
1.7±0.1 g/cm3

[ 沸点 ]:
399.4±37.0 °C at 760 mmHg

[ 熔点 ]:
57.5°C

[ 分子式 ]:
C7H5Cl2FN2O3

[ 分子量 ]:
255.031

[ 闪点 ]:
195.3±26.5 °C

[ 精确质量 ]:
253.966125

[ PSA ]:
85.44000

[ LogP ]:
3.16

[ 外观性状 ]:
白色粉末带有肥皂的气味

[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C

[ 折射率 ]:
1.608

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

氯氟吡氧乙酸MSDS

氯氟吡氧乙酸毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AF2500000
CHEMICAL NAME :
Acetic acid, ((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)-
CAS REGISTRY NUMBER :
69377-81-7
LAST UPDATED :
199412
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C7-H5-Cl2-F-N2-O3
MOLECULAR WEIGHT :
255.04

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2405 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A791,1986
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>296 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PBCWDF Proceedings of the British Crop Protection Conference - Weeds. (British Crop Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1976- Volume(issue)/page/year: -,939,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 39(235),30,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
458 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PBCWDF Proceedings of the British Crop Protection Conference - Weeds. (British Crop Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1976- Volume(issue)/page/year: -,939,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PBCWDF Proceedings of the British Crop Protection Conference - Weeds. (British Crop Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1976- Volume(issue)/page/year: -,939,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A791,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 39(235),30,1985

氯氟吡氧乙酸安全信息

[ 危害声明 ]:
H412

[ 警示性声明 ]:
P273

[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves

[ 风险声明 (欧洲) ]:
R52/53

[ 安全声明 (欧洲) ]:
S61

[ 危险品运输编码 ]:
NONH for all modes of transport

[ RTECS号 ]:
AF2500000

[ 海关编码 ]:
2942000000

氯氟吡氧乙酸制备

由2-甲磺酰基-3,5-二氯-4-氨基-6-氟吡啶与羟基乙酸乙酯作用制得2-乙氧羰基甲氧基-3,5-二氯-4-氨基-6-氟吡啶,再在乙醇溶液中,将上述产物加入氢氧化钠水溶液中,于55℃反应,冷却,酸化得产品氟草定。

氯氟吡氧乙酸海关

[ 海关编码 ]: 2942000000

氯氟吡氧乙酸文献

Method development for determination of fluroxypyr in water.

J. Environ. Sci. Health B 38(4) , 429-40, (2003)

Improved methods for extraction and clean up of fluroxypyr residue in water have been established. Two methods of fluroxypyr extraction were used, namely, Direct Measurement of fluroxypyr and Concentr...

Determination of starane (fluroxypyr) herbicide using flow injection spectrophotometry.

Anal. Sci. 22(1) , 145-6, (2006)

The starane herbicide was spectrophotometrically determined by the diazotization method in a flow injection assembly. Since starane is a substituted pyridyl compound the NH2 group at the p-position wa...

A pathway-specific microarray analysis highlights the complex and co-ordinated transcriptional networks of the developing grain of field-grown barley.

J. Exp. Bot. 60 , 153-67, (2009)

The aim of the study was to describe the molecular and biochemical interactions associated with amino acid biosynthesis and storage protein accumulation in the developing grains of field-grown barley....


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