丁苯吗琳
丁苯吗琳用途
吗啉类杀菌剂，具有保护、治疗、内吸作用。甾醇还原抑制剂，可用于禾谷类作物、豆类、甜菜的白粉病、黑粉病、锈病、棉花立枯病，谷类黑穗病等。推荐药量7.5g有效成分/100m2。
丁苯吗琳名称
[ CAS 号 ]:
67306-03-0
[ 中文名 ]:
丁苯吗啉
[ 英文名 ]:
fenpropimorph
[中文别名 ]:
[英文别名 ]:
- FUNBAS
- MISTRAL T
- FENPROPIMORPH
- forbel750
- MISTRAL
- MILDOFIX
- BAS 421F
- CORBEL
丁苯吗琳物理化学性质
[ 密度 ]:
0.928 g/cm3
[ 沸点 ]:
392.7ºC at 760 mmHg
[ 熔点 ]:
25°C
[ 分子式 ]:
C20H33NO
[ 分子量 ]:
303.48200
[ 闪点 ]:
115.6ºC
[ 精确质量 ]:
303.25600
[ PSA ]:
12.47000
[ LogP ]:
4.20980
[ 折射率 ]:
1.489
[ 储存条件 ]:
0-6°C
丁苯吗琳毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- QE2060000
- CHEMICAL NAME :
- Morpholine, 4-(3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropyl)-2, 6-dimethyl-
- CAS REGISTRY NUMBER :
- 67306-03-0
- LAST UPDATED :
- 199512
- DATA ITEMS CITED :
- 7
- MOLECULAR FORMULA :
- C20-H33-N-O
- MOLECULAR WEIGHT :
- 303.54
- WISWESSER LINE NOTATION :
- T6N DOTJ A1Y1&1R DX1&1&1& C1 E1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 3540 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 42(254),33,1988
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2900 mg/m3
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A201,1985
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 4200 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PBCDDQ Proceedings-British Crop Protection Conference-Pests and Diseases. (British Crop., Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1977- Volume(issue)/page/year: -,541,1979
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 5890 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 42(254),33,1988
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1180 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PBCDDQ Proceedings-British Crop Protection Conference-Pests and Diseases. (British Crop., Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1977- Volume(issue)/page/year: -,541,1979
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - duck
- DOSE/DURATION :
- 17780 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 42(254),33,1988
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - domestic
- DOSE/DURATION :
- 39 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 42(254),33,1988
丁苯吗琳安全信息
[ 危险品运输编码 ]:
UN 2902
[ 包装等级 ]:
III
[ 危险类别 ]:
6.1(b)
[ 海关编码 ]:
29349990
丁苯吗琳合成路线
丁苯吗琳上下游产品
丁苯吗琳上游产品
丁苯吗琳下游产品
丁苯吗琳制备
Vilsmeier反应 以二甲基甲酰胺为溶剂，20℃时将三氯氧磷加入到溶剂中，升温，于70～80℃滴加4-特丁基苯乙酮，反应5h，反应毕，用30%氢氧化钠处理，得含量96%的4-特丁基苯基-1-氯代-2-甲基丙烯醛。
还原反应 4-特丁基苯基-1-氯代-2-甲基丙烯醛在钯/碳催化下加氢还原制得4-特丁基苯基异丁醛。
丁苯吗啉的合成 4-特丁基苯基异丁醛与2，6-二甲基吗啉反应合成丁苯吗啉。
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相关化合物
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