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2-溴-4'-甲基苯乙酮

2-溴-4'-甲基苯乙酮名称

[ CAS 号 ]:
619-41-0

[ 中文名 ]:
2-溴-4'-甲基苯乙酮

[ 英文名 ]:
2-bromo-4'-methylacetophenone

[中文别名 ]:

[英文别名 ]:

Ethanone, 2-bromo-1-(4-methylphenyl)-
2-bromo-4'-methylacetophenone
EINECS 226-267-5
2-Bromo-1-(4-methylphenyl)ethanone
MFCD00009312
Acetophenone, 2-bromo-4'-methyl-

2-溴-4'-甲基苯乙酮物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
263.6±15.0 °C at 760 mmHg

[ 熔点 ]:
45-49 °C(lit.)

[ 分子式 ]:
C₉H₉BrO

[ 分子量 ]:
213.071

[ 闪点 ]:
74.4±7.7 °C

[ 精确质量 ]:
211.983673

[ PSA ]:
17.07000

[ LogP ]:
2.65

[ 外观性状 ]:
白色至淡黄色晶体粉末

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.563

[ 储存条件 ]:
-20?C Freezer, Under Inert Atmosphere

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents, strong bases.

2-溴-4'-甲基苯乙酮MSDS

2-溴-4'-甲基苯乙酮安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S27-S37/39

[ 危险品运输编码 ]:
UN 2811

[ WGK德国 ]:
3

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2914700090

2-溴-4'-甲基苯乙酮合成路线

2-溴-4'-甲基苯乙酮上下游产品

2-溴-4'-甲基苯乙酮上游产品

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2-溴-4'-甲基苯乙酮海关

[ 海关编码 ]: 2914700090

[ 中文概述 ]:
2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

2-溴-4'-甲基苯乙酮文献

Efficient solid-phase synthesis of 2-substituted-3-hydroxy-4(1H)-quinolinone-7-carboxamides with two diversity positions.

J. Comb. Chem. 9(5) , 793-6, (2007)

A highly efficient solid-phase synthesis of 2-substituted-3-hydroxy-4(1H)-quinolinone-7-carboxamides was developed using anthranilates and bromoketones as the key synthons. Primary amines immobilized ...

Use of fluorous silica gel to separate fluorous thiol quenching derivatives in solution-phase parallel synthesis Zhang W, et al.

Tetrahedron 58(20) , 3871-75, (2002)

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