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2,7-硝基芴

2,7-硝基芴用途

用于有机合成。

2,7-硝基芴名称

[ CAS 号 ]:
5405-53-8

[ 中文名 ]:
2,7-二硝基芴

[ 英文名 ]:
2,7-dinitro-9H-fluorene

[中文别名 ]:

[英文别名 ]:

9H-Fluorene, 2,7-dinitro-
EINECS 226-457-8
2,7-dinitro-9H-fluorene
MFCD00001121

2,7-硝基芴物理化学性质

[ 密度 ]:
1.5±0.1 g/cm3

[ 沸点 ]:
451.5±38.0 °C at 760 mmHg

[ 熔点 ]:
330-334°C

[ 分子式 ]:
C₁₃H₈N₂O₄

[ 分子量 ]:
256.214

[ 闪点 ]:
229.9±19.6 °C

[ 精确质量 ]:
256.048401

[ PSA ]:
91.64000

[ LogP ]:
3.62

[ 外观性状 ]:
淡黄色粉末

[ 蒸汽压 ]:
0.0±1.1 mmHg at 25°C

[ 折射率 ]:
1.705

[ 储存条件 ]:
室温

2,7-硝基芴MSDS

详细MSDS(安全技术说明书)

2,7-硝基芴毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: LL7175000

CHEMICAL NAME :: Fluorene, 2,7-dinitro-

CAS REGISTRY NUMBER :: 5405-53-8

BEILSTEIN REFERENCE NO. :: 2057852

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C13-H8-N2-O4

MOLECULAR WEIGHT :: 256.23

WISWESSER LINE NOTATION :: L B656 HHJ ENW KNW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2700 mg/kg/17W-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Gastrointestinal - tumors Skin and Appendages - tumors

MUTATION DATA

TYPE OF TEST :: Unscheduled DNA synthesis

TEST SYSTEM :: Rodent - mouse Liver

DOSE/DURATION :: 2500 ug/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 190,159,1987

2,7-硝基芴安全信息

[ 符号 ]:

GHS08

[ 信号词 ]:
Warning

[ 危害声明 ]:
H351

[ 警示性声明 ]:
P281

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R40

[ 安全声明 (欧洲) ]:
S7-S22-S36/37/39-S45

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
LL7175000

[ 海关编码 ]:
2904209090

2,7-硝基芴海关

[ 海关编码 ]: 2904209090

[ 中文概述 ]:
2904209090 其他仅含硝基或亚硝基的衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2904209090 derivatives containing only nitro or only nitroso groups。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

2,7-硝基芴文献

Voltammetric detection of damage to DNA caused by nitro derivatives of fluorene using an electrochemical DNA biosensor.

Anal. Bioanal. Chem 397(1) , 233-41, (2010)

An electrochemical DNA biosensor based on the screen printed carbon paste electrode (SPCPE) with an immobilized layer of calf thymus double-stranded DNA has been used for in vitro investigation of the...

Preneoplastic lesions and DNA adduct formation of the airborne genotoxic agents 2-nitrofluorene and 2,7-dinitrofluorene.

Carcinogenesis 14(12) , 2627-32, (1993)

The urinary mutagenicity (unconjugated forms) after administration of 2,7-dinitrofluorene (2,7-dNF) orally or i.p. was lower compared to 2-nitrofluorene (NF) administration. When partial hepatectomy (...

Reductions of nitro and 9-Oxo groups of environmental nitrofluorenes by the rat mammary gland in vitro.

Chem. Res. Toxicol. 13(8) , 793-800, (2000)

Nitrofluorenes and C-9-oxidized nitrofluorenes are widespread environmental genotoxins which may be relevant for breast cancer on the basis of their carcinogenicities, particularly of 2, 7-dinitrofluo...

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