4-氯-3,5-二硝基三氟甲苯

4-氯-3,5-二硝基三氟甲苯用途

【用途一】
用作有机合成中间体
【用途二】
3，5-二硝基-4-氯三氟甲苯是植物生长调节剂氟节胺和除草剂氟乐灵的中间体。
【用途三】
本品主要用于生产农药，是旱田除草剂氟乐灵的中间体，该药是优良的旱田除草剂。本品也是医药、染料的重要中间体。

4-氯-3,5-二硝基三氟甲苯名称

[ CAS 号 ]:
393-75-9

[ 中文名 ]:
4-氯-3,5-二硝基三氟甲苯

[ 英文名 ]:
3,5-Dinitro-4-chlorobenzotrifluoride

[中文别名 ]:

[英文别名 ]:

Benzene, 2-chloro-1,3-dinitro-5-(trifluoromethyl)-
4-chloro-3,5-dinitro-benzotrifluorid
2-chloro-1,3-dinitro-5-trifluoromethylbenzene
2,6-dinitro-4-trifluoromethyl-1-chlorobenzene
2-Chloro-1,3-dinitro-5-(trifluoromethyl)benzene
5-dinitrobenzotrifluoride
1,3-dinitro-2-chloro-5-trifluoromethylbenzene
1,3-Dinitro-2-chloro
EINECS 206-889-3
MFCD00007068

4-氯-3,5-二硝基三氟甲苯物理化学性质

[ 密度 ]:
1.7±0.1 g/cm3

[ 沸点 ]:
278.6±35.0 °C at 760 mmHg

[ 熔点 ]:
50-55 °C(lit.)

[ 分子式 ]:
C₇H₂ClF₃N₂O₄

[ 分子量 ]:
270.550

[ 闪点 ]:
122.3±25.9 °C

[ 精确质量 ]:
269.965515

[ PSA ]:
91.64000

[ LogP ]:
2.64

[ 外观性状 ]:
本品为淡黄色固体，m.p.56～58℃，相对密度 1.6085，溶于苯、甲苯等有机溶剂。

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.533

[ 储存条件 ]:
室温

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents.

4-氯-3,5-二硝基三氟甲苯MSDS

详细MSDS(安全技术说明书)

4-氯-3,5-二硝基三氟甲苯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XS9065000

CHEMICAL NAME :: Toluene, 4-chloro-3,5-dinitro-alpha,alpha,alpha-trifluoro-

CAS REGISTRY NUMBER :: 393-75-9

LAST UPDATED :: 199801

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C7-H2-Cl-F3-N2-O4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 930 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold Behavioral - ataxia Lungs, Thorax, or Respiration - dyspnea

REFERENCE :: AISSAW Annali dell'Istituto Superiore di Sanita. (Istituto Poligrafico e Zecca dello Stato, Piazza Verdi, 10 Rome, Italy) V.1- 1965- Volume(issue)/page/year: 19,351,1983

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 161 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - hypermotility, diarrhea

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0546185 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 450 mg/kg/3D-I

TOXIC EFFECTS :: Blood - methemoglobinemia-carboxyhemoglobin Blood - changes in bone marrow (not otherwise specified)

REFERENCE :: EESADV Ecotoxicology and Environmental Safety. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1977- Volume(issue)/page/year: 17,21,1989

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2520 mg/kg/21D-C

TOXIC EFFECTS :: Liver - changes in liver weight Blood - normocytic anemia Blood - methemoglobinemia-carboxyhemoglobin

REFERENCE :: EESADV Ecotoxicology and Environmental Safety. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1977- Volume(issue)/page/year: 12,105,1986 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.05 mg/m3;Skin JAN 1993

4-氯-3,5-二硝基三氟甲苯安全信息

[ 符号 ]:

GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H310

[ 警示性声明 ]:
P280-P302 + P350-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T,Xi

[ 风险声明 (欧洲) ]:
R22:Harmful if swallowed. R24:Toxic in contact with skin. R36/37/38:Irritating to eyes, respiratory system and skin .

[ 安全声明 (欧洲) ]:
S36/37-S45

[ 危险品运输编码 ]:
UN 2811 6.1/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
XS9065000

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2904909090

4-氯-3,5-二硝基三氟甲苯上下游产品

4-氯-3,5-二硝基三氟甲苯上游产品

4-氯-3,5-二硝基三氟甲苯下游产品

4-氯-3,5-二硝基三氟甲苯制备

以对氯三氟甲基苯为原料，经一硝化制得4-氯-3-硝基三氟甲基苯，再经二硝化制得产品。

原料消耗定额：对氯三氟甲基苯780kg/t；硝酸1000kg/t；硫酸4500kg/t。

4-氯-3,5-二硝基三氟甲苯海关

[ 海关编码 ]: 2904909090

[ 中文概述 ]:
2904909090 其他烃的磺化、硝化、亚硝化衍生物（不论是否卤化）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

4-氯-3,5-二硝基三氟甲苯文献

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In vitro mutational studies with trifluralin and trifluorotoluene derivatives.

Ann. Ist. Super. Sanita 18(1) , 123-6, (1982)

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Ann. Ist. Super. Sanita 19(2-3) , 351-4, (1983)

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