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(S,S,S)-(+)-(3,5-二氧杂-4-磷杂环庚二烯并[2,1-a:3,4-a']二萘-4-基)二(1-苯基乙基)胺

名称

[ CAS 号 ]:
380230-02-4

[ 中文名 ]:
3,4-A]二萘-4-基)双[(1S)-1-苯基乙基]胺,二氯甲基加合物

[ 英文名 ]:
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine

[中文别名 ]:

[英文别名 ]:

MFCD04117688
(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE

物理化学性质

[ 沸点 ]:
710.7±63.0 °C at 760 mmHg

[ 熔点 ]:
88-89ºC

[ 分子式 ]:
C₃₆H₃₀NO₂P

[ 分子量 ]:
539.603

[ 闪点 ]:
383.6±33.7 °C

[ 精确质量 ]:
539.201416

[ PSA ]:
29.52000

[ LogP ]:
10.33

[ 蒸汽压 ]:
0.0±2.3 mmHg at 25°C

[ 储存条件 ]:
室温，惰性气体

MSDS

详细MSDS(安全技术说明书)

安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 风险声明 (欧洲) ]:
36/37/38

[ 安全声明 (欧洲) ]:
26-36/37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

文献

Tandem asymmetric conjugate addition--silylation of enantiomerically enriched zinc enolates. Synthetic importance and mechanistic implications.

Org. Lett. 4 , 3835, (2002)

[formula: see text] The zinc enolates, resulting from the copper-catalyzed enantioselective conjugate addition of dialkyl zinc reagents to cyclic and acyclic enones, could be trapped, quantitatively, ...

Copper-catalyzed enantioselective conjugate addition of dialkylzinc reagents to (2-pyridyl)sulfonyl imines of chalcones.

J. Org. Chem. 70 , 7451, (2005)

[reaction: see text] The enantioselective catalytic 1,4-addition to alpha,beta-unsaturated ketimines is an unprecedented process. Herein, we document the copper-catalyzed addition of dialkylzinc reage...

Synlett , 1375, (2001)

更多文献

(S,S,S)-(+)-(3,5-二氧杂-4-磷杂环庚二烯并[2,1-a:3,4-a']二萘-4-基)二(1-苯基乙基)胺

名称

物理化学性质

MSDS

详细MSDS(安全技术说明书)

安全信息

文献

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