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2-丙炔基氯甲酸酯

2-丙炔基氯甲酸酯名称

[ CAS 号 ]:
35718-08-2

[ 中文名 ]:
炔丙基氯甲酸酯

[ 英文名 ]:
2-Propynyl chloroformate

[中文别名 ]:

[英文别名 ]:

propargyloxycarbonyl chloride
2-propynyl chloroformate
MFCD00270127
Carbonochloridic acid, 2-propyn-1-yl ester
chlorocarbonic acid prop-2-ynyl ester
prop-2-yn-1-yl carbonochloridate
2-Propyn-1-yl carbonochloridate
prop-2-ynyl chloroformate
propargylchloroformate
2-Propynyl chloroformate

2-丙炔基氯甲酸酯物理化学性质

[ 密度 ]:
1.271±0.06 g/cm

[ 沸点 ]:
118-122 ºC

[ 分子式 ]:
C₄H₃ClO₂

[ 分子量 ]:
118.518

[ 闪点 ]:
32.3±16.0 ºC

[ 精确质量 ]:
117.982155

[ PSA ]:
26.30000

[ LogP ]:
1.29

[ 外观性状 ]:
无色油状液体

[ 蒸汽压 ]:
23.6±0.2 mmHg at 25°C

[ 折射率 ]:
1.450

[ 储存条件 ]:
2-8°C，惰性气体

[ 水溶解性 ]:
Sparingly soluble (26 g/L) (25 ºC)

2-丙炔基氯甲酸酯安全信息

[ 符号 ]:

GHS02, GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H302-H311-H314-H331

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T: Toxic;

[ 风险声明 (欧洲) ]:
10-22-23/24-34

[ 安全声明 (欧洲) ]:
26-36/37/39-45

[ 危险品运输编码 ]:
UN 3390 6.1/PG 1

[ 海关编码 ]:
2915900090

2-丙炔基氯甲酸酯合成路线

详细合成路线

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2-丙炔基氯甲酸酯海关

[ 海关编码 ]: 2915900090

[ 中文概述 ]:
2915900090. 其他饱和无环一元羧酸及其酸酐（酰卤、过氧）化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

2-丙炔基氯甲酸酯文献

A Study of Solvent Effects in the Solvolysis of Propargyl Chloroformate.

ISRN Org. Chem. 2011 , (2011)

The specific rates of solvolysis of propargyl chloroformate (1) are analyzed in 22 solvents of widely varying nucleophilicity and ionizing power values at 25.0 _C using the extended Grunwald-Winstein ...

Organogold (I) complexes of a C 2-symmetric diacetylide ligand derived from 1, 1'-bi-2-naphthol. Burchell TJ, et al.

Inorganica Chim. Acta 359(9) , 2812-2818, (2006)

Synthesis and applications of propargyl pentafluorophenyl carbonate for peptide synthesis. Bhat RG, et al.

Tetrahedron Lett. 43(13) , 2467-2469, (2002)

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