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三氟甲磺酸三甲基硅酯

三氟甲磺酸三甲基硅酯名称

[ CAS 号 ]:
27607-77-8

[ 中文名 ]:
三氟甲磺酸三甲基硅酯

[ 英文名 ]:
Trimethylsilyl trifluoromethanesulfonate

[中文别名 ]:

[英文别名 ]:

MFCD00000406
Trifluoromethanesulfonic acid trimethylsilylester
trifluoromethanesulfonic acid trimethylsilyl ester
Trimethylsilyl Triflate
[(Trifluoromethane-sulfonyl)oxy]trimethylsilane
trimethylsilyl trifluoromethane-sulphonate
EINECS 248-565-4
Silane TMS-triflate
Trimethylsllytrifluoromethanesulphonate
Trimethylsilyl trifluoromethanesulfonate

三氟甲磺酸三甲基硅酯物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
140.0±35.0 °C at 760 mmHg

[ 分子式 ]:
C₄H₉F₃O₃SSi

[ 分子量 ]:
222.258

[ 闪点 ]:
38.5±25.9 °C

[ 精确质量 ]:
221.999374

[ PSA ]:
51.75000

[ LogP ]:
2.54

[ 外观性状 ]:
透明略黄色液体

[ 蒸汽压 ]:
7.8±0.2 mmHg at 25°C

[ 折射率 ]:
1.379

[ 储存条件 ]:
2-8°C

[ 水溶解性 ]:
REACTS

三氟甲磺酸三甲基硅酯MSDS

三氟甲磺酸三甲基硅酯安全信息

[ 符号 ]:

GHS02, GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H314

[ 补充危害声明 ]:
Reacts violently with water.

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R10;R14;R34

[ 安全声明 (欧洲) ]:
S16-S26-S36/37/39-S45-S8

[ 危险品运输编码 ]:
UN 2920 8/PG 2

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
29310095

三氟甲磺酸三甲基硅酯合成路线

三氟甲磺酸三甲基硅酯上下游产品

三氟甲磺酸三甲基硅酯上游产品

三氟甲磺酸三甲基硅酯下游产品

三氟甲磺酸三甲基硅酯海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

三氟甲磺酸三甲基硅酯文献

Trimethylsilyl trifluoromethanesulfonate-promoted reductive 2'-O-arylmethylation of ribonucleoside derivatives.

Nucleosides Nucleotides Nucleic Acids 30(6) , 446-56, (2011)

Arylmethyl groups such as benzyl, p-methoxybenzyl, and 1-pyrenylmethyl groups were introduced to the 2'-O-position of nucleosides by reductive etherification. Combining corresponding aromatic aldehyde...

Trimethylsilyl trifluoromethanesulfonate (TMSOTf) assisted facile deprotection of N,O-acetonides.

J. Org. Chem. 73(2) , 752-5, (2008)

Employing TMSOTf as an easily available reagent, we have developed a mild and efficient method for the deprotection of both terminal and internal N,0-acetonide functionalities. Various regularly used ...

Nucleophilic substitution at the anomeric position of 1,2-O-isopropylidenefuranose derivatives. A novel stereoselective synthesis of cyclic phosphates analogous to cAMP.

Carbohydr. Res. 341(18) , 2883-90, (2006)

1,2-O-Isopropylidenefuranose derivatives were treated with various nucleophiles in the presence of either BF(3).OEt(2) or trimethylsilyl trifluoromethanesulfonate (TMSOTf) leading to substitution prod...

更多文献

三氟甲磺酸三甲基硅酯

三氟甲磺酸三甲基硅酯名称

三氟甲磺酸三甲基硅酯物理化学性质

三氟甲磺酸三甲基硅酯MSDS

详细MSDS(安全技术说明书)

三氟甲磺酸三甲基硅酯安全信息

三氟甲磺酸三甲基硅酯合成路线

详细合成路线

三氟甲磺酸三甲基硅酯上下游产品

三氟甲磺酸三甲基硅酯上游产品

三氟甲磺酸三甲基硅酯下游产品

三氟甲磺酸三甲基硅酯海关

三氟甲磺酸三甲基硅酯文献

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