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D(-)-对羟基苯甘氨酸

D(-)-对羟基苯甘氨酸用途

D-4-Hydroxyphenylglycine (D-(-)-4-Hydroxyphenylglycine) 是生产半合成 β-内酰胺类抗生素的最重要原料之一,例如阿莫西林 (HY-B0467A) 和头孢羟氨苄 (HY-B1190)。

D(-)-对羟基苯甘氨酸名称

[ CAS 号 ]:
22818-40-2

[ 中文名 ]:
D(-)-对羟基苯甘氨酸

[ 英文名 ]:
(D)-(-)-α-4-hydroxyphenyl glycine

[中文别名 ]:

[英文别名 ]:

(D)-(-)-α-4-hydroxyphenyl glycine
D(-)-2-amino-(4-hydroxyphenyl)acetic acid
(R)-2-(4-Hydroxyphenyl)glycine
D(-)-4-Hydroxyphenylglycine
Benzeneacetic acid, α-amino-4-hydroxy-, (αR)-
(2R)-2-Amino-2-(4
D-N-(4-Hydroxyphenyl)glycine
(2R)-Amino(4-hydroxyphenyl)acetic acid
D(-)-2-(4-hydroxyphenyl)glycine
(R)-(-)-2-Amino-2-(4-hydroxyphenyl)acetic acid

D(-)-对羟基苯甘氨酸生物活性

[ 描述 ]:

D-4-Hydroxyphenylglycine (D-(-)-4-Hydroxyphenylglycine) 是生产半合成 β-内酰胺类抗生素的最重要原料之一,例如阿莫西林 (HY-B0467A) 和头孢羟氨苄 (HY-B1190)。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[参考文献]

[1]. Yu H, et al. Efficient biocatalytic production of D-4-hydroxyphenylglycine by whole cells of recombinant Ralstonia pickettii. Folia Microbiol (Praha). 2009;54(6):509-515.

D(-)-对羟基苯甘氨酸物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
365.8±32.0 °C at 760 mmHg

[ 熔点 ]:
240 °C (dec.)(lit.)

[ 分子式 ]:
C₈H₉NO₃

[ 分子量 ]:
167.162

[ 闪点 ]:
175.0±25.1 °C

[ 精确质量 ]:
167.058243

[ PSA ]:
83.55000

[ LogP ]:
0.20

[ 外观性状 ]:
白色至灰白色结晶粉末

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.633

[ 储存条件 ]:
室温

[ 水溶解性 ]:
5 g/L (20 ºC)

D(-)-对羟基苯甘氨酸MSDS

详细MSDS(安全技术说明书)

D(-)-对羟基苯甘氨酸安全信息

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
29225000

D(-)-对羟基苯甘氨酸上下游产品

D(-)-对羟基苯甘氨酸上游产品

D(-)-对羟基苯甘氨酸下游产品

D(-)-对羟基苯甘氨酸制备

大茴香醛经环合、水解制成DL-对羟基苯甘氨酸，再用甲醇酯化，用酒石酸拆分，得到D（-）-对羟基苯甘氨酸。国内大部分D-对羟基苯甘氨酸的生产企业目前基本都采用乙醛酸工艺生产。

D(-)-对羟基苯甘氨酸海关

[ 海关编码 ]: 2922509090

[ 中文概述 ]:
2922509090. 其他氨基醇酚、氨基酸酚及其他含氧基氨基化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件：AB. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验

[ Summary ]:
2922509090. other amino-alcohol-phenols, amino-acid-phenols and other amino-compounds with oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

D(-)-对羟基苯甘氨酸文献

Role of glucose metabolism in the recovery of postischemic LV mechanical function: effects of insulin and other metabolic modulators.

Am. J. Physiol. Heart Circ. Physiol. 294(6) , H2576-86, (2008)

The role of proton (H+) production from glucose metabolism in the recovery of myocardial function during postischemic reperfusion and its alteration by insulin and other metabolic modulators were exam...

The enduracidin biosynthetic gene cluster from Streptomyces fungicidicus.

Microbiology 152(Pt 10) , 2969-83, (2006)

The biosynthetic gene cluster for the 17 aa peptide antibiotic enduracidin has been cloned and sequenced from Streptomyces fungicidicus ATCC 21013. The 84 kb gene cluster contains 25 ORFs and is locat...

Cardiac lipoprotein lipase activity in the hypertrophied heart may be regulated by fatty acid flux.

Biochim. Biophys. Acta 1821(4) , 627-36, (2012)

Cardiac hypertrophy is characterised by an imbalance between lipid uptake and fatty acid β-oxidation leading to an accumulation of lipids, particularly triacylglycerol (TAG). It is unclear whether upt...

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