磷化铝

磷化铝用途

【用途一】
杀虫剂,主要用于粮仓熏蒸
【用途二】
为熏蒸杀虫剂,既能熏蒸原粮、成品粮,又能熏蒸种子粮和各种仓储器材。也用于其他密闭场所杀虫、鼠洞灭鼠和树干灭天牛等。粮食熏蒸时用量为10~30 g/t粮;仓库熏蒸时一般用量为1~4片/m3

磷化铝名称

[ CAS 号 ]:
20859-73-8

[ 中文名 ]:
磷化铝

[ 英文名 ]:
Aluminum phosphide

[中文别名 ]:

[英文别名 ]:

磷化铝物理化学性质

[ 密度 ]:
2.42

[ 熔点 ]:
2000℃

[ 分子式 ]:
AlP

[ 分子量 ]:
57.95

[ LogP ]:
0.55080

[ 外观性状 ]:
黄色或灰色晶体

[ 储存条件 ]:
库房通风低温干燥,与酸分开存放

[ 稳定性 ]:
Flammable solid. Contact with acids liberates highly toxic gas (phosphine). Incompatible with acids, moisture, oxidizing agents.

磷化铝MSDS

磷化铝毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BD1400000
CHEMICAL NAME :
Aluminum phosphide
CAS REGISTRY NUMBER :
20859-73-8
LAST UPDATED :
199803
DATA ITEMS CITED :
22
MOLECULAR FORMULA :
Al-P
MOLECULAR WEIGHT :
57.95
WISWESSER LINE NOTATION :
AL P

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - woman
DOSE/DURATION :
60 mg/kg
TOXIC EFFECTS :
Vascular - other changes Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - gastritis
REFERENCE :
HUTODJ Human Toxicology. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants., RG 21 2XS, UK) V.1- 1981- Volume(issue)/page/year: 7,343,1988
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
21 mg/kg
TOXIC EFFECTS :
Vascular - other changes Gastrointestinal - gastritis
REFERENCE :
HUTODJ Human Toxicology. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants., RG 21 2XS, UK) V.1- 1981- Volume(issue)/page/year: 7,343,1988
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - woman
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Cardiac - pulse rate increase, without fall in BP Liver - jaundice, other or unclassified Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis)
REFERENCE :
HUTODJ Human Toxicology. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants., RG 21 2XS, UK) V.1- 1981- Volume(issue)/page/year: 7,343,1988
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
86 mg/kg
TOXIC EFFECTS :
Behavioral - coma Vascular - other changes Gastrointestinal - nausea or vomiting
REFERENCE :
HUTODJ Human Toxicology. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants., RG 21 2XS, UK) V.1- 1981- Volume(issue)/page/year: 7,343,1988
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
2800 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 3,38,1976/1977 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Al)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Al)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Al)/m3 JAN 1993 OEL-FRANCE:TWA 2 mg(Al)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Al)/m3 JAN 1993 OEL-RUSSIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Al)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84460 No. of Facilities: 280 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 12600 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84460 No. of Facilities: 190 (estimated) No. of Industries: 3 No. of Occupations: 4 No. of Employees: 623 (estimated)

磷化铝安全信息

[ 危害码 (欧洲) ]:
T+,F,N

[ 风险声明 (欧洲) ]:
R15/29

[ 安全声明 (欧洲) ]:
S3/9/14-S30-S36/37-S45-S61

[ 危险品运输编码 ]:
1397

[ 包装等级 ]:
I

[ 危险类别 ]:
4.3

[ 海关编码 ]:
2848000010

磷化铝制备

1.赤磷和铝粉混合后,经高温煅烧,即得磷化铝。

2.本品可由赤磷和铝粉按比例混料,均匀混合后点火燃烧反应生成。反应物经粉碎、加入缓释剂氨基甲酸铵和黏结剂混合后压片成品。

磷化铝海关

[ 海关编码 ]: 2848000010

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