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三甲基碘化亚砜

三甲基碘化亚砜用途

【用途一】
主要用于合成氟康唑。

三甲基碘化亚砜名称

[ CAS 号 ]:
1774-47-6

[ 中文名 ]:
三甲基碘化亚砜

[ 英文名 ]:
Trimethylsulfoxonium iodide

[中文别名 ]:

[英文别名 ]:

Trimethyl sulphoxonium ioidie
OS1&1&1 &&iodide
Trimethylsulfoxonium Iodide
Trimethyloxosulfonium iodide
trimethyl-oxo-sulfonium iodide
trimethyloxosulphonium iodide
MFCD00011899
trimethyl sulphoxonium iodide
dimethyloxosulfonium methylide
Corey-Chaykovsky reagent

三甲基碘化亚砜物理化学性质

[ 熔点 ]:
208-212 °C (dec.)(lit.)

[ 分子式 ]:
C₃H₉IOS

[ 分子量 ]:
220.072

[ 精确质量 ]:
219.941864

[ PSA ]:
36.28000

[ 外观性状 ]:
白色至黄色晶体

[ 储存条件 ]:
室温

[ 水溶解性 ]:
15 g/L (20 ºC)

三甲基碘化亚砜MSDS

三甲基碘化亚砜毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: WS3585000

CHEMICAL NAME :: Sulfoxonium, trimethyl-, iodide

CAS REGISTRY NUMBER :: 1774-47-6

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C3-H9-O-S.I

MOLECULAR WEIGHT :: 220.08

WISWESSER LINE NOTATION :: OS1&1&1 &Q &I

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 900 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: IJRBA3 International Journal of Radiation Biology and Related Studies in Physics, Chemistry and Medicine. (Taylor & Francis Inc., 242 Cherry St., Philadelphia, PA 19106) V.1- 1959- Volume(issue)/page/year: 3,41,1961

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 180 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04108

三甲基碘化亚砜安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful

[ 风险声明 (欧洲) ]:
R22;R36/37/38

[ 安全声明 (欧洲) ]:
S37/39-S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
WS3585000

[ 海关编码 ]:
2930909090

三甲基碘化亚砜合成路线

三甲基碘化亚砜上下游产品

三甲基碘化亚砜上游产品

三甲基碘化亚砜下游产品

三甲基碘化亚砜海关

[ 海关编码 ]: 2909199090

[ 中文概述 ]:
2909199090. 其他无环醚及其卤化衍生物（包括磺化，硝化或亚硝化衍生物）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

三甲基碘化亚砜文献

Optical phonons, crystal-field transitions, and europium luminescence-excitation processes in Eu2BaCoO5: Experiment and theory.

Tetrahedron 50 , 9157, (1994)

Renin inhibitors containing C-termini derived from mercaptoheterocycles.

J. Med. Chem. 35 , 2103, (1992)

A series of transition-state analogues having heterocyclythio C-termini has been synthesized and evaluated for inhibition of human renin. Addition of mercaptoheterocycles to a chiral Boc-amino epoxide...

Tetrahedron 49 , 5067, (1993)

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