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氯乙酸苄酯

氯乙酸苄酯用途

有机合成。

氯乙酸苄酯名称

[ CAS 号 ]:
140-18-1

[ 中文名 ]:
氯乙酸苄酯

[ 英文名 ]:
Benzyl chloroacetate

[中文别名 ]:

氯乙酸苯甲酯

[英文别名 ]:

benzyl monochloroacetate
chloroacetic acid benzyl ester
Acetic acid, 2-chloro-, phenylmethyl ester
Acetic acid,chloro-,phenylmethyl ester
MFCD00157062
Benzyl α-chloroacetate
Benzyl monochloracetate
Benzyl chloroacetate
chloroacetic acid phenylmethyl ester
Monochloroacetate

氯乙酸苄酯物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
252.8±15.0 °C at 760 mmHg

[ 熔点 ]:
90ºC

[ 分子式 ]:
C₉H₉ClO₂

[ 分子量 ]:
184.620

[ 闪点 ]:
117.9±15.8 °C

[ 精确质量 ]:
184.029114

[ PSA ]:
26.30000

[ LogP ]:
2.20

[ 外观性状 ]:
无色液体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.525

[ 储存条件 ]:
通风低温干燥

[ 水溶解性 ]:
insoluble

氯乙酸苄酯MSDS

氯乙酸苄酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AF8750000

CHEMICAL NAME :: Acetic acid, chloro-, benzyl ester

CAS REGISTRY NUMBER :: 140-18-1

BEILSTEIN REFERENCE NO. :: 2091502

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C9-H9-Cl-O2

MOLECULAR WEIGHT :: 184.63

WISWESSER LINE NOTATION :: G1VO1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 8,99,1956

氯乙酸苄酯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
AF8750000

[ 海关编码 ]:
2915400090

氯乙酸苄酯合成路线

氯乙酸苄酯上下游产品

氯乙酸苄酯上游产品

氯乙酸苄酯下游产品

氯乙酸苄酯海关

[ 海关编码 ]: 2915400090

[ 中文概述 ]:
2915400090 其他一氯代乙酸的盐和酯（包括二氯代乙酸或三氯代乙酸的盐和酯）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2915400090 mono-, di- or trichloroacetic acids, their salts and esters

氯乙酸苄酯文献

Synthesis and anti-herpes simplex activity of analogues of phosphonoacetic acid.

J. Med. Chem. 20(5) , 660-3, (1977)

The synthesis of monoesters (P and C) of phosphonoacetic acid (PA) is given. The carboxyl esters were prepared by two methods: the reaction of chloroacetates with tris(trimethylsilyl) phosphite, follo...

Influence of the substrate structure on carboxypeptidase Y catalyzed peptide bond formation. Breddam K, et al.

Carlsberg Res. Commun. 45(5) , 361-67, (1980)

Stereoselective total syntheses of the (±)-di-O-methyl ethers of agatharesinol, sesquirin-A, and hinokiresinol, and of (±)-tri-O-methylsequirin-E, characteristic norlignans of coniferae. Beracierta AP and Whiting DA.

J. Chem. Soc. Perkin Trans. I 10 , 1257-63, (1978)

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