氯氟磺酰

氯氟磺酰用途

氟氯化硫酰一般不作溶剂使用。由于对有机化合物的溶解能力强、熔点低、在酸性条件下稳定，故近年来常用作低温研究阴碳离子用溶剂。

氯氟磺酰名称

[ CAS 号 ]:
13637-84-8

[ 中文名 ]:
氯氟磺酰

[ 英文名 ]:
sulfuryl chloride fluoride

[英文别名 ]:

chlorosulfonyl fluoride
EINECS 237-126-2
Sulfuryl fluorochloride
MFCD00011607
SULFURYL CHLORIDE FLUORIDE
sulphuryl chloride fluoride
Sulfuryl fluoride chloride
Chloro fluoro sulfone
Sulfuryl chlorofluoride
Chlorosulphonyl fluoride

氯氟磺酰物理化学性质

[ 密度 ]:
1.784 g/cm3

[ 沸点 ]:
7 °C

[ 熔点 ]:
-125 °C

[ 分子式 ]:
ClFO₂S

[ 分子量 ]:
118.51500

[ 闪点 ]:
113 °C

[ 精确质量 ]:
117.92900

[ PSA ]:
42.52000

[ LogP ]:
1.52030

[ 蒸汽压 ]:
1420mmHg at 25°C

[ 折射率 ]:
1.391

[ 储存条件 ]:
?20°C

氯氟磺酰MSDS

详细MSDS(安全技术说明书)

氯氟磺酰毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: WT4900000

CHEMICAL NAME :: Sulfuryl chloride fluoride

CAS REGISTRY NUMBER :: 13637-84-8

LAST UPDATED :: 199712

DATA ITEMS CITED :: 28

MOLECULAR FORMULA :: Cl-F-O2-S

MOLECULAR WEIGHT :: 118.51

WISWESSER LINE NOTATION :: S O2-G-F

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 520 mg/m3/10M

REFERENCE :: NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,JUN1942 *** REVIEWS *** ACGIH TLV-TWA 2.5 mg(F)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 2.5 mg(F)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,116,1971 OSHA PEL (Gen Indu):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2.5 mg(F)/m3 JAN 1993 OEL-BELGIUM:TWA 2.5 mg(F)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(F)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(F)/m3 JAN 1993 OEL-FRANCE:TWA 2.5 mg(F)/m3 JAN 1993 OEL-GERMANY:TWA 2.5 mg(F)/m3 JAN 1993 OEL-HUNGARY:TWA 1 mg(F)/m3;STEL 2 mg(F)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2.5 mg(F)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 2.5 mg(F)/m3 JAN 1993 OEL-POLAND:TWA 1 mg(F)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(F)/m3 JAN 1993 OEL-SWITZERLAND:TWA 1.8 ppm (1.5 mg(F)/m3);STEL 9.0 ppm JAN 1993 OEL-THAILAND:TWA 2.5 mg(F)/m3 JAN 1993 OEL-TURKEY:TWA 2.5 mg(F)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2.5 mg(F)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO FLUORIDES, INORGANIC-air:10H TWA 2.5 mg(F)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

氯氟磺酰安全信息

[ 符号 ]:

GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301 + H311 + H331-H314

[ 补充危害声明 ]:
Reacts violently with water.

[ 警示性声明 ]:
Missing Phrase - N15.00950417-P260-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338 + P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T: Toxic;

[ 风险声明 (欧洲) ]:
R14

[ 安全声明 (欧洲) ]:
S26-S27-S28-S36/37/39-S45

[ 危险品运输编码 ]:
UN 2922 8/PG 1

[ WGK德国 ]:
3

[ RTECS号 ]:
WT4900000

[ 危险类别 ]:
2.3

氯氟磺酰合成路线

详细合成路线

氯氟磺酰上下游产品

氯氟磺酰上游产品

氯氟磺酰下游产品

氯氟磺酰文献

J. Fluor. Chem. 68 , 277, (1994)

Mater. Res. Soc. Symp. Proc. 247 , 293, (1992)

A convenient preparation of sulfuryl chloride fluoride Reddy VP, et al.

J. Fluor. Chem. 56(2) , 195-197, (1992)

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