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硫化铜

硫化铜用途

【用途一】
用于复写纸和普通圆珠笔油的着色
【用途二】
制备混合催化剂，苯胺黑染料显色，船底保护油漆。

硫化铜名称

[ CAS 号 ]:
1317-40-4

[ 中文名 ]:
硫化铜

[ 英文名 ]:
Copper sulfide (CuS)

[中文别名 ]:

硫化銅

[英文别名 ]:

MFCD00016066
Cupric sulfide
EINECS 215-271-2
C.I. Pigment Blue 34
Copper(II) Sulfide,Ultra Dry,Metals Basis)

硫化铜物理化学性质

[ 密度 ]:
4.6

[ 熔点 ]:
220ºC

[ 分子式 ]:
CuS

[ 分子量 ]:
95.61100

[ 精确质量 ]:
94.90170

[ PSA ]:
32.09000

[ LogP ]:
0.64570

[ 外观性状 ]:
粉末/结晶固体

[ 折射率 ]:
1.45

[ 储存条件 ]:
库房低温,通风,干燥

[ 稳定性 ]:
Stable, but may be moisture senstive. Incompatible with strong acids, strong oxidizing agents.

硫化铜MSDS

硫化铜毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GL8912000

CHEMICAL NAME :: Copper(II) sulfide

CAS REGISTRY NUMBER :: 1317-40-4

LAST UPDATED :: 199706

DATA ITEMS CITED :: 34

MOLECULAR FORMULA :: Cu-S

MOLECULAR WEIGHT :: 95.60

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: DNA damage

TEST SYSTEM :: Rodent - hamster Ovary

DOSE/DURATION :: 10 mg/L

REFERENCE :: CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1980- Volume(issue)/page/year: 3,657,1982 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-AUSTRALIA:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-AUSTRALIA:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-BELGIUM:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-BELGIUM:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-DENMARK:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-DENMARK:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-FINLAND:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-FINLAND:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-FRANCE:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-FRANCE:TWA 1 mg(Cu)/m3;STEL 2 mg(Cu)/m3 (dust) JAN 1993 OEL-GERMANY:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-GERMANY:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-HUNGARY:TWA 0.2 mg(Cu)/m3;STEL 0.4 mg(Cu)/m3 (dust) JAN 1993 OEL-INDIA:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-THE NETHERLANDS:TWA 02 mg(Cu)/m3 (fume) JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-THE PHILIPPINES:TWA 1.0 mg(Cu)/m3 (fume) JAN 1993 OEL-POLAND:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-RUSSIA:STEL 0.5 ppm (1 mg(Cu)/m3) (dust) JAN 1993 OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-SWEDEN:TWA 1 mg(Cu)/m3 (total dust) JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Cu)/m3;STEL 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-SWITZERLAND:TWA 1 mg(Cu)/m3;STEL 1 mg(Cu)/m3 JAN 1993 OEL-THAILAND:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-THAILAND:TWA 1 mg(Cu)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg(Cu)/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - T2084 No. of Facilities: 723 (estimated) No. of Industries: 5 No. of Occupations: 5 No. of Employees: 4151 (estimated) No. of Female Employees: 246 (estimated)

硫化铜安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
F+

[ 安全声明 (欧洲) ]:
S22-S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
GL8912000

硫化铜合成路线

硫化铜上下游产品

硫化铜上游产品

硫化铜下游产品

硫化铜制备

1.采用双管电炉，在石英管内，一端放硫磺，一端放入铜箔卷，将系统抽成真空后，将硫磺的一端加热到425℃，铜的一端加热到450℃，连续加热24h后，缓缓冷却之，则得CuS。

2.在硫酸铜溶液中通入硫化氢，或往Cu2+溶液中加入Na2S或(NH4)2S，将产生的沉淀过滤、干燥，便可得CuS产品。

硫化铜文献

Enzyme-responsive copper sulphide nanoparticles for combined photoacoustic imaging, tumor-selective chemotherapy and photothermal therapy.

Chem. Commun. (Camb.) 49(33) , 3455-7, (2013)

Gelatin-stabilized copper sulphide nanoparticles with conjugated doxorubicin have been developed for combined photoacoustic imaging, enzyme-responsive drug release and photothermal therapy.

Water soluble sodium sulfate nanorods as a versatile template for the designing of copper sulfide nanotubes.

J. Nanosci. Nanotechnol. 14(6) , 4455-61, (2014)

The present study reports the use of water soluble sodium sulfate (Na2SO4) nanorods as a versatile template for generation of tubular copper sulfide (CuS) nanostructures. The Na2SO4 nanorods were synt...

Copper uptake by DMT1: a compensatory mechanism for CTR1 deficiency in human umbilical vein endothelial cells.

Metallomics 7 , 1285-9, (2015)

Copper transport 1 (CTR1) plays a critical role in copper uptake by cells, but several studies demonstrated that divalent metal transporter 1 (DMT1) also transports copper in some cells and under cert...

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硫化铜