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2-氯蒽醌

2-氯蒽醌用途

【用途一】
用于染料工业
【用途二】
用作重要的染料中间体。主要用于生产2-氨基蒽醌，并进一步生产还原染料，如还原蓝RSN、还原蓝BC等，也可用于制造茜素。

2-氯蒽醌名称

[ CAS 号 ]:
131-09-9

[ 中文名 ]:
2-氯蒽醌

[ 英文名 ]:
2-chloroanthraquinone

[中文别名 ]:

[英文别名 ]:

2-Chloroanthracene-9,10-dione
2-Chloro-9,10-anthraquinone
9,10-Anthracenedione, 2-chloro-
MFCD00001227
EINECS 205-010-0
2-chloroanthraquinone

2-氯蒽醌物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
425.7±34.0 °C at 760 mmHg

[ 熔点 ]:
209-211 °C(lit.)

[ 分子式 ]:
C₁₄H₇ClO₂

[ 分子量 ]:
242.657

[ 闪点 ]:
179.7±26.2 °C

[ 精确质量 ]:
242.013458

[ PSA ]:
34.14000

[ LogP ]:
4.11

[ 外观性状 ]:
米色粉末

[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C

[ 折射率 ]:
1.666

[ 储存条件 ]:
库房低温通风干躁

[ 水溶解性 ]:
insoluble

2-氯蒽醌MSDS

2-氯蒽醌毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CB6151000

CHEMICAL NAME :: Anthraquinone, 2-chloro-

CAS REGISTRY NUMBER :: 131-09-9

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C14-H7-Cl-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >10 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 55(7),93,1990

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4310 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 49(4),90,1984

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >10 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 55(7),93,1990

2-氯蒽醌安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37;R43

[ 安全声明 (欧洲) ]:
S26-S36-S37/39-S24

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
1

[ RTECS号 ]:
CB6151000

[ 海关编码 ]:
2914700090

2-氯蒽醌合成路线

2-氯蒽醌上下游产品

2-氯蒽醌上游产品

2-氯蒽醌下游产品

2-氯蒽醌制备

苯酐与氯苯在无水三氯化铝存在下反应，得氯苯甲酰苯甲酸铝复盐，经水解酸化，再以发烟硫酸脱水、闭环、离析、过滤得成品。

2-氯蒽醌海关

[ 海关编码 ]: 2914700090

[ 中文概述 ]:
2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

2-氯蒽醌文献

Photoreactivity of anthraquinones for the analysis of ginsenosides using photoreduction fluorescence detection-HPLC Park MK, et al.

Arch. Pharm. Res. 19(6) , 562-565, (1996)

更多文献