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2,2'-二氨基二苯二硫醚

2,2'-二氨基二苯二硫醚用途

【用途一】
用作染料中间体、橡胶硫化剂

2,2'-二氨基二苯二硫醚名称

[ CAS 号 ]:
1141-88-4

[ 中文名 ]:
双(2-氨基苯基)二硫

[ 英文名 ]:
2,2'-Disulfanediyldianiline

[中文别名 ]:

[英文别名 ]:

2-[(2-aminophenyl)disulfanyl]aniline
2,2'-Diaminodiphenyl disulphide
Di(2-aminophenyl) Disulfide
EINECS 214-529-1
2,2'-Diaminodiphenyl Disulfide
MFCD00007703
2,2'-Dithiodianiline
2-Aminophenyl Disulfide
2,2'-Disulfanediyldianiline
Benzenamine, 2,2'-dithiobis-

2,2'-二氨基二苯二硫醚物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
398.0±27.0 °C at 760 mmHg

[ 熔点 ]:
91-92 °C(lit.)

[ 分子式 ]:
C₁₂H₁₂N₂S₂

[ 分子量 ]:
248.367

[ 闪点 ]:
194.5±23.7 °C

[ 精确质量 ]:
248.044189

[ PSA ]:
102.64000

[ LogP ]:
3.05

[ 外观性状 ]:
无色液体

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.741

[ 储存条件 ]:
室温

2,2'-二氨基二苯二硫醚MSDS

2,2'-二氨基二苯二硫醚毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BX9540000

CHEMICAL NAME :: Aniline, 2,2'-dithiobis-

CAS REGISTRY NUMBER :: 1141-88-4

BEILSTEIN REFERENCE NO. :: 0914032

LAST UPDATED :: 199703

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C12-H12-N2-S2

MOLECULAR WEIGHT :: 248.38

WISWESSER LINE NOTATION :: ZR BSSR BZ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1005,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 50 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 178 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00263 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 434 mg/kg/7D-I

TOXIC EFFECTS :: Endocrine - changes in spleen weight Blood - pigmented or nucleated red blood cells Nutritional and Gross Metabolic - changes in iron

REFERENCE :: JJATDK JAT, Journal of Applied Toxicology. (John Wiley & Sons Ltd., Baffins Lane, Chichester, W. Sussex PO19 1UD, UK) V.1- 1981- Volume(issue)/page/year: 5,414,1985

2,2'-二氨基二苯二硫醚安全信息

[ 符号 ]:

GHS05, GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H318-H410

[ 警示性声明 ]:
P273-P280-P301 + P310-P305 + P351 + P338-P501

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R41

[ 安全声明 (欧洲) ]:
S26-S39

[ 危险品运输编码 ]:
UN2811 - class 6.1 - PG 3 - EHS - Toxic solids, organic, n.o.s., HI: all

[ WGK德国 ]:
2

[ RTECS号 ]:
BX9540000

[ 海关编码 ]:
2930909090

2,2'-二氨基二苯二硫醚合成路线

2,2'-二氨基二苯二硫醚上下游产品

2,2'-二氨基二苯二硫醚上游产品

2,2'-二氨基二苯二硫醚下游产品

2,2'-二氨基二苯二硫醚制备

【方法一】
安乐嗪的中间体。橡胶的硫化剂。

2,2'-二氨基二苯二硫醚海关

[ 海关编码 ]: 2930909090

[ 中文概述 ]:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

2,2'-二氨基二苯二硫醚文献

Effect of 2,2'-diaminodiphenyldisulfide, a resin hardener, on rats.

J. Toxicol. Environ. Health A 7(1) , 69-81, (1981)

Guided by structure-activity relationships among carcinogenic aromatic amines, a sulfur-containing aromatic diamine was designed as a possible noncarcinogenic replacement for the resin hardener 4,4'-m...

Novel Tm(III) Membrane Sensor Based on 2,2'-Dianiline Disulfide and Its Application for the Fluoride Monitoring of Mouth Wash Preparations Ganjali, M.R., et al.

Bull. Korean Chem. Soc. 27 (9) , 1418-1422, (2006)

A general and efficient synthesis of 2-phenylbenzothiazoles from diphenyl disulfides. Chang, Yi-Hua, et al.

Synth. Commun. 23 , 663-670, (1993)

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