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甲酰苯胺

甲酰苯胺用途

【用途一】
用于有机合成。

甲酰苯胺名称

[ CAS 号 ]:
103-70-8

[ 中文名 ]:
N-苯基甲酰胺

[ 英文名 ]:
Formamide, N-phenyl-

[中文别名 ]:

N-甲酰苯胺

[英文别名 ]:

N-Phenylformamide
ForManilide
EINECS 203-136-0
MFCD00003276

甲酰苯胺物理化学性质

[ 密度 ]:
1.144 g/mL at 25 °C(lit.)

[ 沸点 ]:
166 °C14 mm Hg(lit.)

[ 熔点 ]:
46-48 °C(lit.)

[ 分子式 ]:
C₇H₇NO

[ 分子量 ]:
121.13700

[ 闪点 ]:
>230 °F

[ 精确质量 ]:
121.05300

[ PSA ]:
29.10000

[ LogP ]:
1.96380

[ 外观性状 ]:
白色或淡黄色晶体或粉末

[ 蒸汽压 ]:
0.00662mmHg at 25°C

[ 折射率 ]:
1.594

[ 储存条件 ]:
0-10°C

[ 稳定性 ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

甲酰苯胺MSDS

甲酰苯胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BY1780000

CHEMICAL NAME :: Aniline, N-formyl-

CAS REGISTRY NUMBER :: 103-70-8

BEILSTEIN REFERENCE NO. :: 0906934

LAST UPDATED :: 199710

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C7-H7-N-O

MOLECULAR WEIGHT :: 121.15

WISWESSER LINE NOTATION :: VHMR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 400 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: XPHBAO U.S. Public Health Service, Public Health Bulletin. (Washington, DC) Volume(issue)/page/year: 271,19,1941

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 400 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - muscle weakness Lungs, Thorax, or Respiration - respiratory stimulation

REFERENCE :: XPHBAO U.S. Public Health Service, Public Health Bulletin. (Washington, DC) Volume(issue)/page/year: 271,19,1941

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Amphibian - frog

DOSE/DURATION :: 800 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: XPHBAO U.S. Public Health Service, Public Health Bulletin. (Washington, DC) Volume(issue)/page/year: 271,19,1941

甲酰苯胺安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
22

[ 安全声明 (欧洲) ]:
S22-S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
BY1780000

[ 海关编码 ]:
2924299090

甲酰苯胺合成路线

甲酰苯胺制备

由苯胺与甲酸反应而得。将2.8kg苯胺，2kg甲苯，3L甲酸加入装有分馏柱的烧瓶中，加热脱水半小时，反应后蒸馏回收甲苯至110℃。冷却，滤出结晶，减压蒸馏得甲酰苯胺。

甲酰苯胺海关

[ 海关编码 ]: 2924299090

[ 中文概述 ]:
2924299090. 其他环酰胺（包括环氨基甲酸酯）（包括其衍生物以及他们的盐）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

甲酰苯胺文献

ZEKE photoelectron spectroscopy of the cis and trans isomers of formanilide.

Angew. Chem. Int. Ed. Engl. 41(1) , 166-8, (2002)

Phosphazene base-catalyzed condensation of trimethylsilylacetate with carbonyl compounds.

Chem. Commun. (Camb.) (29) , 3128-30, (2006)

The t-Bu-P4 base was found to be an excellent catalyst for the condensation of trimethylsilylacetate or trimethylacetonitrile with carbonyl compounds to form functionalized alkenes and beta-enaminoest...

Isomer selective infrared spectroscopy of supersonically cooled cis- and trans-N-phenylamides in the region from the amide band to NH stretching vibration.

Phys. Chem. Chem. Phys. 11(29) , 6098-106, (2009)

We measured the infrared (IR) spectra of supersonically cooled N-phenylformamide (formanilide) and N-phenylacetamide (acetanilide) in the amide band and X-H stretch vibration regions by using IR-UV de...

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