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茴香硫醚

茴香硫醚用途

【用途一】
用作农药、医药、染料中间体
【用途二】
高效启动剂，用于酸催化裂解N-Z, O-benzyl 和 O-methyl保护基团。

茴香硫醚名称

[ CAS 号 ]:
100-68-5

[ 中文名 ]:
茴香硫醚

[ 英文名 ]:
Thioanisole

[中文别名 ]:

[英文别名 ]:

Methyl phenyl sulfide
methylsulfanylbenzene
methyl phenyl sulphide
Sulfide, methyl phenyl
(Methylthio)benzene
Methyl phenyl thioether
(Methylsulfanyl)benzene
Benzene, (methylthio)-
Methyl phenylsulfide
Methylthiobenzene

茴香硫醚物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
193.0±0.0 °C at 760 mmHg

[ 熔点 ]:
−15 °C(lit.)

[ 分子式 ]:
C₇H₈S

[ 分子量 ]:
124.203

[ 闪点 ]:
57.2±0.0 °C

[ 精确质量 ]:
124.034668

[ PSA ]:
25.30000

[ LogP ]:
2.70

[ 外观性状 ]:
无色至黄色液体

[ 蒸汽压 ]:
0.7±0.3 mmHg at 25°C

[ 折射率 ]:
1.569

[ 储存条件 ]:
2-8°C

[ 稳定性 ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
INSOLUBLE

茴香硫醚MSDS

茴香硫醚毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DA6200000

CHEMICAL NAME :: Benzene, (methylthio)-

CAS REGISTRY NUMBER :: 100-68-5

LAST UPDATED :: 199710

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C7-H8-S

MOLECULAR WEIGHT :: 124.21

WISWESSER LINE NOTATION :: 1SR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 891 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PCBPBS Pesticide Biochemistry and Physiology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1971- Volume(issue)/page/year: 1,356,1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 56 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00184

茴香硫醚安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36/39-S36/37

[ 危险品运输编码 ]:
UN 1993 3/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
DA6200000

[ 包装等级 ]:
III

[ 危险类别 ]:
9

[ 海关编码 ]:
29309070

茴香硫醚合成路线

茴香硫醚上下游产品

茴香硫醚上游产品

茴香硫醚下游产品

茴香硫醚制备

1.以苯硫酚及硫酸二甲酯为原料，在碱性条件下，进行酯化反应而得。

　2.苯胺法　由苯胺重氮化制得重氮盐；再与甲硫醇钠反应制得，最后一步反应式如下：

茴香硫醚海关

[ 海关编码 ]: 2930909090

[ 中文概述 ]:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

茴香硫醚文献

Quantification of plasma HIV RNA using chemically engineered peptide nucleic acids.

Nat. Commun. 5 , 5079, (2014)

The remarkable stability of peptide nucleic acids (PNAs) towards enzymatic degradation makes this class of molecules ideal to develop as part of a diagnostic device. Here we report the development of ...

The influence of linker length on the properties of cathepsin S cleavable177Lu-labeled HPMA copolymers for pancreatic cancer imaging

Biomaterials 35(22) , 5760-70, (2014)

N-(2-hydroxypropyl)-methacrylamide (HPMA) copolymers have shown promise for application in the detection and staging of cancer. However, non-target accumulation, particularly in the liver and spleen, ...

Calculating virtual log P in the alkane/water system (log P(N)(alk)) and its derived parameters deltalog P(N)(oct-alk) and log D(pH)(alk).

J. Med. Chem. 48 , 3269-79, (2005)

Growing interest in the use of both the logarithm of the partition coefficient of the neutral species in the alkane/water system (log P(N)(alk)) and the difference between log P(N)(oct) (the logarithm...

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