Allyl methacrylate

Modify Date: 2024-01-02 10:45:56

Allyl methacrylate Structure
Allyl methacrylate structure
Common Name Allyl methacrylate
CAS Number 96-05-9 Molecular Weight 126.15300
Density 0.938 g/mL at 25 °C(lit.) Boiling Point 59-61 °C43 mm Hg(lit.)
Molecular Formula C7H10O2 Melting Point -65 °C
MSDS Chinese USA Flash Point 33.9±0.0 °C
Symbol GHS02 GHS06 GHS08 GHS09
GHS02, GHS06, GHS08, GHS09
Signal Word Danger

 Names

Name Allyl methacrylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.938 g/mL at 25 °C(lit.)
Boiling Point 59-61 °C43 mm Hg(lit.)
Melting Point -65 °C
Molecular Formula C7H10O2
Molecular Weight 126.15300
Flash Point 33.9±0.0 °C
Exact Mass 126.06800
PSA 26.30000
LogP 1.29170
Vapour Pressure 4.6 mm Hg ( 20 °C)
Index of Refraction n20/D 1.436(lit.)
Water Solubility 4 g/L (20 ºC)

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UD3483000
CHEMICAL NAME :
2-Propenoic acid, 2-methyl-, 2-propenyl ester
CAS REGISTRY NUMBER :
96-05-9
BEILSTEIN REFERENCE NO. :
1747406
LAST UPDATED :
199710
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C7-H10-O2
MOLECULAR WEIGHT :
126.17
WISWESSER LINE NOTATION :
1UY1&VO2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,371,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,371,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
70 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 34(8),59,1990
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1800 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 34(8),59,1990
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
57 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 34(8),59,1990
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
5500 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 34(8),59,1990
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
500 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969

 Safety Information

Symbol GHS02 GHS06 GHS08 GHS09
GHS02, GHS06, GHS08, GHS09
Signal Word Danger
Hazard Statements H226-H302-H311-H330-H373-H410
Precautionary Statements P210-P260-P280-P302 + P352 + P312-P304 + P340 + P310-P370 + P378
Target Organs Liver
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes T:Toxic
Risk Phrases R10;R21/22;R23;R50
Safety Phrases S36/37-S45-S61
RIDADR UN 2929 6.1/PG 2
WGK Germany 2
RTECS UD3483000
Packaging Group II
Hazard Class 6.1
HS Code 2916140000

 Synthetic Route

 Customs

HS Code 2916140000
Summary 2916140000. other esters of methacrylic acid. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:80.0%

 Articles3

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Prediction of the reduced glutathione (GSH) reactivity of dental methacrylate monomers using NMR spectra - Relationship between toxicity and GSH reactivity.

Dent. Mater. J. 28(6) , 722-9, (2009)

It has been established that the toxicity of acrylate and methacrylate monomers is driven by their reactivity towards glutathione (GSH). With this relationship, the objective of this study was to pred...

Glutathione depletion in rat hepatocytes: a mixture toxicity study with alpha, beta-unsaturated esters.

Xenobiotica 31(5) , 295-307, (2001)

1. Glutathione (GSH) depletion is often reported as an early cytotoxic effect, caused by many reactive organic chemicals. In the present study, GSH depletion in primary rat hepatocytes was used as an ...

Subchronic dermal toxicity study of allyl methacrylate in rabbits.

Drug Chem. Toxicol. 5(2) , 165-82, (1982)

A 28-day subchronic dermal toxicity of allyl methacrylate (AMA) was conducted in New Zealand white rabbits. Groups of six male and six female rabbits were treated with the test material at dose levels...

 Synonyms

EINECS 202-473-0
MFCD00008592
prop-2-enyl 2-methylprop-2-enoate
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