p-Fluoropropiophenone

Modify Date: 2024-01-02 18:13:10

p-Fluoropropiophenone Structure
p-Fluoropropiophenone structure
 Common Name p-Fluoropropiophenone
CAS Number 456-03-1 Molecular Weight 152.166
Density 1.1±0.1 g/cm3 Boiling Point 215.9±13.0 °C at 760 mmHg
Molecular Formula C9H9FO Melting Point N/A
MSDS Chinese USA Flash Point 76.7±0.0 °C
Symbol GHS05 GHS07
GHS05, GHS07		 Signal Word Danger

 Names

Name 4'-Fluoropropiophenone
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 215.9±13.0 °C at 760 mmHg
Molecular Formula C9H9FO
Molecular Weight 152.166
Flash Point 76.7±0.0 °C
Exact Mass 152.063736
PSA 17.07000
LogP 2.25
Vapour Pressure 0.1±0.4 mmHg at 25°C
Index of Refraction 1.489

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H302-H315-H318-H335
Precautionary Statements P261-P280-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S39-S37/39
RIDADR 2735
WGK Germany 2
HS Code 2914700090

 Synthetic Route

3-(4-fluorophenyl)-3-hydroxy-1-propene structure

3-(4-fluorophen...

CAS#:5724-03-8

~95%

p-Fluoropropiophenone Structure

p-Fluoropropiop...

CAS#:456-03-1
Literature: Bouziane, Asmae; Carboni, Bertrand; Bruneau, Christian; Carreaux, Francois; Renaud, Jean-Luc Tetrahedron, 2008 , vol. 64, # 51 p. 11745 - 11750
4'-Fluoroacetophenone structure

4'-Fluoroacetop...

CAS#:403-42-9
N,N-Dimethylformamide structure

N,N-Dimethylfor...

CAS#:68-12-2

~65%

p-Fluoropropiophenone Structure

p-Fluoropropiop...

CAS#:456-03-1
Literature: Li, Yang; Xue, Dong; Lu, Wei; Wang, Chao; Liu, Zhao-Tie; Xiao, Jianliang Organic Letters, 2014 , vol. 16, # 1 p. 66 - 69
N-Methoxy-N-methylpropanamide structure

N-Methoxy-N-met...

CAS#:104863-65-2
1-Bromo-4-fluorobenzene structure

1-Bromo-4-fluor...

CAS#:460-00-4

~15%

p-Fluoropropiophenone Structure

p-Fluoropropiop...

CAS#:456-03-1
Literature: Ueno, Satoshi; Shimizu, Ryosuke; Kuwano, Ryoichi Angewandte Chemie, International Edition, 2009 , vol. 48, p. 4543 - 4545 Angewandte Chemie, 2009 , vol. 121, p. 4613 - 4615
alpha-ethyl-p-fluorobenzyl alcohol structure

alpha-ethyl-p-f...

CAS#:701-47-3

~%

p-Fluoropropiophenone Structure

p-Fluoropropiop...

CAS#:456-03-1
Literature: Chang, Lu; Kuang, Yulong; Qin, Bo; Zhou, Xin; Liu, Xiaohua; Lin, Lili; Feng, Xiaoming Organic Letters, 2010 , vol. 12, # 10 p. 2214 - 2217
Fluorobenzene structure

Fluorobenzene

CAS#:462-06-6
Propanoyl chloride structure

Propanoyl chloride

CAS#:79-03-8

~%

p-Fluoropropiophenone Structure

p-Fluoropropiop...

CAS#:456-03-1
Literature: Oelschlaeger,H.; Schmersahl,P. Archiv der Pharmazie und Berichte der Deutschen Pharmazeutischen Gesellschaft, 1963 , vol. 296, p. 324 - 336
1-(4-fluorophenyl)-4-methylpentane-1,3-dione structure

1-(4-fluorophen...

CAS#:114433-94-2

~%

p-Fluoropropiophenone Structure

p-Fluoropropiop...

CAS#:456-03-1
Literature: Sterk, Damjan; Casar, Zdenko; Jukic, Marko; Kosmrlj, Janez Tetrahedron, 2012 , vol. 68, # 9 p. 2155 - 2160
N/A structure

N/A

CAS#:1354455-77-8

~%

p-Fluoropropiophenone Structure

p-Fluoropropiop...

CAS#:456-03-1
Literature: Sterk, Damjan; Casar, Zdenko; Jukic, Marko; Kosmrlj, Janez Tetrahedron, 2012 , vol. 68, # 9 p. 2155 - 2160
3-(4-fluorophenyl)-3-hydroxy-1-propene structure

3-(4-fluorophen...

CAS#:5724-03-8

~0%

p-Fluoropropiophenone Structure

p-Fluoropropiop...

CAS#:456-03-1

alpha-ethyl-p-fluorobenzyl alcohol structure

alpha-ethyl-p-f...

CAS#:701-47-3
Literature: Cadierno, Victorio; Crochet, Pascale; Francos, Javier; Garcia-Garrido, Sergio E.; Gimeno, Jose; Nebra, Noel Green Chemistry, 2009 , vol. 11, # 12 p. 1992 - 2000
Bromoethane structure

Bromoethane

CAS#:74-96-4
4-Fluorobenzonitrile structure

4-Fluorobenzonitrile

CAS#:1194-02-1

~%

p-Fluoropropiophenone Structure

p-Fluoropropiop...

CAS#:456-03-1
Literature: Lagoja, Irene; Pannecouque, Christophe; Griffioen, Gerard; Wera, Stefaan; Rojasdelaparra, Veronica Maria; Van Aerschot, Arthur European Journal of Pharmaceutical Sciences, 2011 , vol. 43, # 5 p. 386 - 392

 Customs

HS Code 2914700090
Summary HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

 Articles1

More Articles
Padmavathy K, et al.

Tetrahedron Lett. 52(4) , (2011)

 Synonyms

p-Fluoropropiophenone
4′-Fluoropropiophenone
para-Fluoropropiophenone
Propiophenone, 4'-fluoro-
4-Fluoropropiophenone
Ethyl 4-Fluorophenyl Ketone
1-(4-fluorophenyl)propan-1-one
1-Propanone, 1- (4-fluorophenyl)-
4’-Fluoropropiophenone
1-(4-Fluorophenyl)-1-propanone
MFCD00000356
EINECS 207-255-9
1-Propanone, 1-(4-fluorophenyl)-
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