(3E)-4-[(Trimethylsilyl)oxy]-3-penten-2-one

Modify Date: 2024-01-09 19:33:10

(3E)-4-[(Trimethylsilyl)oxy]-3-penten-2-one Structure
(3E)-4-[(Trimethylsilyl)oxy]-3-penten-2-one structure
Common Name (3E)-4-[(Trimethylsilyl)oxy]-3-penten-2-one
CAS Number 13257-81-3 Molecular Weight 172.297
Density 0.9±0.1 g/cm3 Boiling Point 205.1±0.0 °C at 760 mmHg
Molecular Formula C8H16O2Si Melting Point N/A
MSDS Chinese USA Flash Point 58.9±0.0 °C
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

 Names

Name 4-Trimethylsilyloxy-3-penten-2-one
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 205.1±0.0 °C at 760 mmHg
Molecular Formula C8H16O2Si
Molecular Weight 172.297
Flash Point 58.9±0.0 °C
Exact Mass 172.091949
PSA 26.30000
LogP 2.24
Vapour Pressure 0.3±0.4 mmHg at 25°C
Index of Refraction 1.426
Storage condition 2-8°C

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H226-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi: Irritant;
Risk Phrases 10-36/37/38
Safety Phrases S26-S36
RIDADR UN 1224 3/PG 3
WGK Germany 3
Packaging Group III
Hazard Class 3.2
HS Code 2931900090

 Synthetic Route

~70%

(3E)-4-[(Trimethylsilyl)oxy]-3-penten-2-one Structure

(3E)-4-[(Trimet...

CAS#:13257-81-3

Literature: Journal of the American Chemical Society, , vol. 115, # 3 p. 830 - 846

~90%

(3E)-4-[(Trimethylsilyl)oxy]-3-penten-2-one Structure

(3E)-4-[(Trimet...

CAS#:13257-81-3

Literature: Journal of Organometallic Chemistry, , vol. 208, # 3 p. 309 - 315

~%

(3E)-4-[(Trimethylsilyl)oxy]-3-penten-2-one Structure

(3E)-4-[(Trimet...

CAS#:13257-81-3

Literature: Tetrahedron, , vol. 52, # 7 p. 2603 - 2628

~%

(3E)-4-[(Trimethylsilyl)oxy]-3-penten-2-one Structure

(3E)-4-[(Trimet...

CAS#:13257-81-3

Literature: Synthesis, , p. 722 - 724

~%

(3E)-4-[(Trimethylsilyl)oxy]-3-penten-2-one Structure

(3E)-4-[(Trimet...

CAS#:13257-81-3

Literature: Journal of Fluorine Chemistry, , vol. 56, # 2 p. 141 - 146

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles1

More Articles
Functionalized silicon-containing imino enols and enamino ketones prepared by hydrolytic condensation. Semenov VV, et al.

Russ. J. Appl. Chem. 80(4) , 647-53, (2007)

 Synonyms

3-Penten-2-one, 4-[(trimethylsilyl)oxy]-, (3E)-
(3E)-4-[(Trimethylsilyl)oxy]-3-penten-2-one
(3E)-4-[(Trimethylsilyl)oxy]pent-3-en-2-one
4-TRIMETHYLSILOXY-3-PENTEN-2-ONE
EINECS 236-252-5
Acetylacetone enol trimethylsilyl ether,TMS acac
4-TriMethylsilyloxy-3-penten-2-one
MFCD00009853