Disulfur dichloride

Modify Date: 2024-01-02 08:10:50

Disulfur dichloride Structure
Disulfur dichloride structure
Common Name Disulfur dichloride
CAS Number 10025-67-9 Molecular Weight 135.03600
Density 1.688 g/mL at 25 °C(lit.) Boiling Point 138 °C(lit.)
Molecular Formula Cl2S2 Melting Point −80 °C(lit.)
MSDS Chinese USA Flash Point 118ºC
Symbol GHS05 GHS06 GHS09
GHS05, GHS06, GHS09
Signal Word Danger

 Names

Name Disulfur Dichloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.688 g/mL at 25 °C(lit.)
Boiling Point 138 °C(lit.)
Melting Point −80 °C(lit.)
Molecular Formula Cl2S2
Molecular Weight 135.03600
Flash Point 118ºC
Exact Mass 133.88200
PSA 50.60000
LogP 2.67540
Vapour density 4.7 (vs air)
Vapour Pressure 6.8 mm Hg ( 20 °C)
Index of Refraction n20/D 1.658(lit.)
Water Solubility reacts

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WS4300000
CHEMICAL NAME :
Sulfur chloride
CAS REGISTRY NUMBER :
10025-67-9
LAST UPDATED :
199712
DATA ITEMS CITED :
25
MOLECULAR FORMULA :
Cl2-S2
MOLECULAR WEIGHT :
135.02
WISWESSER LINE NOTATION :
S2 G2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
150 ppm
REFERENCE :
IPSTB3 International Polymer Science and Technology. (Rapra Technology Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year: 3,93,1976 *** REVIEWS *** ACGIH TLV-CL 5.5 mg/m3 (1 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 1 ppm (6 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 ppm (6 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 ppm (6 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 ppm (6 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 1 ppm (6 mg/m3) JAN 1993 OEL-BELGIUM:STEL 1 ppm (5.5 mg/m3) JAN 1993 OEL-DENMARK:TWA 1 ppm (6 mg/m3) JAN 1993 OEL-FINLAND:TWA 1 ppm (6 mg/m3);STEL 2 ppm (12 mg/m3);Skin JAN 1993 OEL-GERMANY:TWA 1 ppm (6 mg/m3) JAN 1993 OEL-HUNGARY:STEL 5 mg/m3 JAN 1993 OEL-JAPAN:STEL 1 ppm (5.5 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 1 ppm (6 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 6 mg/m3 JAN 1993 OEL-POLAND:TWA 5 mg/m3 JAN 1993 OEL-RUSSIA:STEL 1 ppm (0.3 mg/m3);Skin JAN 1993 OEL-SWITZERLAND:TWA 1 ppm (6 mg/m3);STEL 2 ppm (12 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 1 ppm (6 mg/m3);STEL 3 ppm (18 mg/m3) JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO SULFUR MONOCHLORIDE-air:CL 1 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5495 No. of Facilities: 964 (estimated) No. of Industries: 21 No. of Occupations: 28 No. of Employees: 28182 (estimated) No. of Female Employees: 2203 (estimated)

 Safety Information

Symbol GHS05 GHS06 GHS09
GHS05, GHS06, GHS09
Signal Word Danger
Hazard Statements H301 + H331-H314-H400
Supplemental HS Contact with water liberates toxic gas., Reacts violently with water.
Precautionary Statements P280-P301 + P310 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P403 + P233
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes T:Toxic;C:Corrosive;N:Dangerousfortheenvironment;
Risk Phrases R14;R20;R25;R29;R35;R50
Safety Phrases S26-S36/37/39-S45-S61
RIDADR UN 3390 6.1/PG 1
WGK Germany 3
RTECS WS4300000
Packaging Group I
Hazard Class 8
HS Code 2812104100

 Synthetic Route

 Customs

HS Code 2812104100

 Articles4

More Articles
Synthesis of taurine analogues from alkenes: preparation of 2-aminocycloalkanesulfonic acids.

Adv. Exp. Med. Biol. 483 , 399-401, (2000)

(+/-)trans 2-Aminocyclohexanesulfonic acid and (+/-)trans 2-aminocyclopentanesulfonic acid were prepared from cyclohexene and cyclopentene respectively by sulfur monochloride addition, followed by oxi...

[Eye burn caused by sulfur monochloride].

Bull. Soc. Ophtalmol. Fr. 87(3) , 429-30, (1987)

Hypochlorite-induced oxidation of thiols: formation of thiyl radicals and the role of sulfenyl chlorides as intermediates.

Free Radic. Res. 33(6) , 719-29, (2000)

Activated phagocytic cells generate hypochlorite (HOCl) via release of hydrogen peroxide and the enzyme myeloperoxidase. HOCl plays an important role in bacterial cell killing, but excessive or mispla...

 Synonyms

MFCD00011446
Disulfur dichloride
chlorosulfanyl thiohypochlorite
EINECS 233-036-2