dibenzyl diethylphosphoramidite
dibenzyl diethylphosphoramidite structure
|
Common Name | dibenzyl diethylphosphoramidite | ||
|---|---|---|---|---|
| CAS Number | 67746-43-4 | Molecular Weight | 317.36200 | |
| Density | 1.06 | Boiling Point | 360ºC at 760 mmHg | |
| Molecular Formula | C18H24NO2P | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 34ºC | |
| Symbol |
GHS02, GHS07 |
Signal Word | Warning | |
| Name | Dibenzyl diethylphosphoramidite, |
|---|---|
| Synonym | More Synonyms |
| Density | 1.06 |
|---|---|
| Boiling Point | 360ºC at 760 mmHg |
| Molecular Formula | C18H24NO2P |
| Molecular Weight | 317.36200 |
| Flash Point | 34ºC |
| Exact Mass | 317.15400 |
| PSA | 35.29000 |
| LogP | 4.98870 |
| Vapour Pressure | 0.71 psi ( 55 °C) |
| Index of Refraction | 1.545 |
| Storage condition | glass bottle, -20°C Freezer, Under Inert Atmosphere |
| Water Solubility | Soluble in chloroform. |
| Symbol |
GHS02, GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H226-H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi: Irritant; |
| Risk Phrases | R10;R36/37/38 |
| Safety Phrases | 16-26-37/39 |
| RIDADR | UN 1993 |
| WGK Germany | 3 |
| Packaging Group | III |
| Hazard Class | 3.2 |
|
~75%
dibenzyl diethy... CAS#:67746-43-4 |
| Literature: Perich, John W.; Alewood, Paul F.; Johns, R. B. Australian Journal of Chemistry, 1991 , vol. 44, # 2 p. 233 - 252 |
|
~89%
dibenzyl diethy... CAS#:67746-43-4 |
| Literature: Perich, John W.; Johns, R. B. Australian Journal of Chemistry, 1990 , vol. 43, p. 1623 - 1632 |
|
~%
dibenzyl diethy... CAS#:67746-43-4 |
| Literature: Organic Letters, , vol. 9, # 17 p. 3327 - 3329 |
|
~74%
dibenzyl diethy... CAS#:67746-43-4 |
| Literature: Smirnova, L.I.; Malenkovskaya, M. A.; Predvoditelev, D. A.; Nifant'ev, E. E. Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, p. 1011 - 1019 Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 6 p. 1170 - 1179 |
|
~%
dibenzyl diethy... CAS#:67746-43-4 |
| Literature: Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 178, # 11 p. 2465 - 2477 |
|
~%
dibenzyl diethy... CAS#:67746-43-4 |
| Literature: Russian Journal of General Chemistry, , vol. 76, # 10 p. 1533 - 1536 |
|
~%
dibenzyl diethy... CAS#:67746-43-4 |
| Literature: Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 178, # 11 p. 2465 - 2477 |
| Precursor 6 | |
|---|---|
| DownStream 5 | |
CAS#:90013-45-9
CAS#:26292-51-3
CAS#:620-05-3
CAS#:134150-51-9
CAS#:1623-08-1|
Asymmetric phosphorylation through catalytic P(III) phosphoramidite transfer: enantioselective synthesis of D-myo-inositol-6-phosphate.
Proc. Natl. Acad. Sci. U. S. A. 107(48) , 20620-4, (2010) Despite the ubiquitous use of phosphoramidite chemistry in the synthesis of biophosphates, catalytic asymmetric phosphoramidite transfer remains largely unexplored for phosphate ester synthesis. We ha... |
|
|
Synthesis of Casein-Related Peptides and Phosphopeptides. V. The Efficient Global'Phosphite-Triester'Phosphorylation of Protected Serine Derivatives and Peptides by Using Dibenzyl or Di-t-butyl N, N-Diethylphosphoramidite. Perich JW and Johns RB.
Aust. J. Chem. 43(10) , 1623-32, (1990)
|
|
|
Synthesis of dibenzyl glycosyl phosphites using dibenzyl N, N-diethylphosphoramidite as phosphitylating reagent: an effective route to glycosyl phosphates, nucleotides, and glycosides. Sim MM, et al.
J. Am. Chem. Soc. 115(6) , 2260-67, (1993)
|
| MFCD00191987 |
| N-bis(phenylmethoxy)phosphanyl-N-ethylethanamine |