2'-methyl-biphenyl-4-ylamine

Modify Date: 2024-01-10 10:19:39

2'-methyl-biphenyl-4-ylamine Structure
2'-methyl-biphenyl-4-ylamine structure
 Common Name 2'-methyl-biphenyl-4-ylamine
CAS Number 63019-97-6 Molecular Weight 183.24900
Density 1.057g/cm3 Boiling Point 303.2ºC at 760 mmHg
Molecular Formula C13H13N Melting Point N/A
MSDS N/A Flash Point 144.3ºC

 Names

Name 2'-methyl-biphenyl-4-ylamine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.057g/cm3
Boiling Point 303.2ºC at 760 mmHg
Molecular Formula C13H13N
Molecular Weight 183.24900
Flash Point 144.3ºC
Exact Mass 183.10500
PSA 26.02000
LogP 3.82540
Index of Refraction 1.607

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DU9800000
CHEMICAL NAME :
4-Biphenylamine, 2-methyl-
CAS REGISTRY NUMBER :
63019-97-6
BEILSTEIN REFERENCE NO. :
2717270
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C13-H13-N
MOLECULAR WEIGHT :
183.27
WISWESSER LINE NOTATION :
ZR C1 DR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2400 mg/kg/W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors
REFERENCE :
BMBUAQ British Medical Bulletin. (Longman Group UK Ltd., Longman House, Burnt Mill, Harlow, Essex CM20 2JE, UK) V.1- 1943- Volume(issue)/page/year: 14,141,1958

 Synthetic Route

1,1'-Biphenyl, 2-methyl-4-nitro structure

1,1'-Biphenyl, ...

CAS#:91718-52-4

~95%

2'-methyl-biphenyl-4-ylamine Structure

2'-methyl-biphe...

CAS#:63019-97-6
Literature: Pfizer Inc Patent: US6350907 B1, 2002 ; Location in patent: Example 37 ;
4-Bromo-3-methylaniline structure

4-Bromo-3-methy...

CAS#:6933-10-4
Phenylboronic acid structure

Phenylboronic acid

CAS#:98-80-6

~99%

2'-methyl-biphenyl-4-ylamine Structure

2'-methyl-biphe...

CAS#:63019-97-6
Literature: Rhodia Chimie Patent: US6800784 B1, 2004 ; Location in patent: Page column 9 ;
4-nitrobiphenyl-2-carbaldehyde structure

4-nitrobiphenyl...

CAS#:124391-57-7

~%

2'-methyl-biphenyl-4-ylamine Structure

2'-methyl-biphe...

CAS#:63019-97-6
Literature: Clariant GmbH Patent: US2001/20104 A1, 2001 ;
MNA structure

MNA

CAS#:99-52-5

~%

2'-methyl-biphenyl-4-ylamine Structure

2'-methyl-biphe...

CAS#:63019-97-6
Literature: Melby et al. Journal of the American Chemical Society, 1950 , vol. 72, p. 1032
1-Bromo-2-methyl-4-nitrobenzene structure

1-Bromo-2-methy...

CAS#:7149-70-4

~%

2'-methyl-biphenyl-4-ylamine Structure

2'-methyl-biphe...

CAS#:63019-97-6
Literature: O'Connell, Daniel P.; Leblanc, Daniel F.; Cromley, Debra; Billheimer, Jeffrey; Rader, Daniel J.; Bachovchin, William W. Bioorganic and Medicinal Chemistry Letters, 2012 , vol. 22, # 3 p. 1397 - 1401
Phenylboronic acid structure

Phenylboronic acid

CAS#:98-80-6

~%

2'-methyl-biphenyl-4-ylamine Structure

2'-methyl-biphe...

CAS#:63019-97-6
Literature: O'Connell, Daniel P.; Leblanc, Daniel F.; Cromley, Debra; Billheimer, Jeffrey; Rader, Daniel J.; Bachovchin, William W. Bioorganic and Medicinal Chemistry Letters, 2012 , vol. 22, # 3 p. 1397 - 1401
benzene structure

benzene

CAS#:71-43-2

~%

2'-methyl-biphenyl-4-ylamine Structure

2'-methyl-biphe...

CAS#:63019-97-6
Literature: Melby et al. Journal of the American Chemical Society, 1950 , vol. 72, p. 1032
4-Methylphenylhydrazine structure

4-Methylphenylh...

CAS#:539-44-6
benzene structure

benzene

CAS#:71-43-2

~0%

4-Aminodiphenylmethane structure

4-Aminodiphenyl...

CAS#:1135-12-2
2'-methyl-biphenyl-4-ylamine Structure

2'-methyl-biphe...

CAS#:63019-97-6

Detail
Literature: Ohta, Toshiharu; Miyake, Shinji; Shudo, Koichi Tetrahedron Letters, 1985 , vol. 26, # 47 p. 5811 - 5814

 Synonyms

3-methyl-4-phenylaniline
4-amino-2-methylbiphenyl
2-methyl-biphenyl-4-ylamine
4-phenyl-3-methylaniline
4-amino-2-methyl-1-phenylbenzene
2-Methyl-biphenyl-4-ylamin
2-methylbiphenyl-4-amine
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2'-Methylbiphenyl-4-carboxylic acid ethyl ester
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