1,2-bis(diethoxyphosphoryl)ethyne

Modify Date: 2025-08-26 18:47:07

1,2-bis(diethoxyphosphoryl)ethyne Structure
1,2-bis(diethoxyphosphoryl)ethyne structure
Common Name 1,2-bis(diethoxyphosphoryl)ethyne
CAS Number 4851-53-0 Molecular Weight 298.21000
Density N/A Boiling Point N/A
Molecular Formula C10H20O6P2 Melting Point N/A
MSDS N/A Flash Point N/A

 Names

Name 1,2-bis(diethoxyphosphoryl)ethyne
Synonym More Synonyms

 Chemical & Physical Properties

Molecular Formula C10H20O6P2
Molecular Weight 298.21000
Exact Mass 298.07400
PSA 90.68000
LogP 3.43700

 MSDS


Section 1: Product Identification
Chemical Name:Bis(diethoxyphosphoryl)acetylene, 99%
CAS Registry Number:4851-53-0
Formula:C10H20O6P2
EINECS Number:none
Chemical Family:organophosphine ligand
Synonym:1,2-Bis(diethoxyphosphinyl)ethyne; (Diethoxy-phosphorylethynyl)-phosphonic acid diethyl ester

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound4851-53-0100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unususal fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep in a cool, dry, well
Handling and Storage:
ventilated place.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:yellow liquid
Molecular Weight:298.21
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:no data
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:moisture sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:prolonged exposure to moisture
Incompatibility:water, oxidizing agents and halogens
Decomposition Products:carbon monoxide, carbon dioxide, phosphorus oxides and organic fumes

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Synthetic Route

~86%

1,2-bis(diethoxyphosphoryl)ethyne Structure

1,2-bis(diethox...

CAS#:4851-53-0

Literature: Kyba, Even P.; Rines, Steven P.; Owens, Philip W.; Chou, Shang-Shing P. Tetrahedron Letters, 1981 , vol. 22, # 20 p. 1875 - 1878

~%

1,2-bis(diethoxyphosphoryl)ethyne Structure

1,2-bis(diethox...

CAS#:4851-53-0

Literature: Acheson, R. Morrin; Ansell, Peter J.; Murray, Jane R. Journal of Chemical Research, Miniprint, 1986 , # 10 p. 3001 - 3019

~%

1,2-bis(diethoxyphosphoryl)ethyne Structure

1,2-bis(diethox...

CAS#:4851-53-0

Literature: Acheson, R. Morrin; Ansell, Peter J.; Murray, Jane R. Journal of Chemical Research, Miniprint, 1986 , # 10 p. 3001 - 3019

~%

1,2-bis(diethoxyphosphoryl)ethyne Structure

1,2-bis(diethox...

CAS#:4851-53-0

Literature: Kruglov,S.V. et al. J. Gen. Chem. USSR (Engl. Transl.), 1973 , vol. 43, p. 1480 - 1490,1470 - 1478

 Synonyms

tetraethyl ethynyldiphosphonate
Tetraethyl ethyne-1,2-diylbisphosphonate
tetraethyl acetylenediphosphonate
tetraethyl ethynylbisphosphonate
tetraethyl ethynediyldiphosphonate
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