Hoveyda-Grubbs II
Hoveyda-Grubbs II structure
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Common Name | Hoveyda-Grubbs II | ||
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| CAS Number | 301224-40-8 | Molecular Weight | 626.622 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C31H38Cl2N2ORu | Melting Point | 216-220ºC(lit.) | |
| MSDS | USA | Flash Point | N/A | |
| Name | [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(2-propan-2-yloxyphenyl)methylidene]ruthenium |
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| Synonym | More Synonyms |
| Melting Point | 216-220ºC(lit.) |
|---|---|
| Molecular Formula | C31H38Cl2N2ORu |
| Molecular Weight | 626.622 |
| Exact Mass | 626.140503 |
| PSA | 15.71000 |
| LogP | 8.18270 |
| InChIKey | ZRPFJAPZDXQHSM-UHFFFAOYSA-L |
| SMILES | Cc1cc(C)c(N2CCN(c3c(C)cc(C)cc3C)C2=[Ru](Cl)(Cl)=Cc2ccccc2OC(C)C)c(C)c1 |
| Storage condition | 2~8 ℃ |
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
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| Hazard Codes | Xi |
| RIDADR | NONH for all modes of transport |
| HS Code | 2933990090 |
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Hoveyda-Grubbs II CAS#:301224-40-8 |
| Literature: Angewandte Chemie - International Edition, , vol. 43, # 45 p. 6161 - 6165 |
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Hoveyda-Grubbs II CAS#:301224-40-8 |
| Literature: Organometallics, , vol. 29, # 19 p. 4339 - 4345 |
| Precursor 3 | |
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| DownStream 0 | |
| HS Code | 2933990090 |
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| Summary | 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |
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Highly efficient ruthenium catalysts for the formation of tetrasubstituted olefins via ring-closing metathesis.
Org. Lett. 9 , 1589, (2007) [reaction: see text] A series of ruthenium-based metathesis catalysts with N-heterocyclic carbene (NHC) ligands have been prepared in which the N-aryl groups have been changed from mesityl to mono-ort... |
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Sequential catalysis: a metathesis/dihydroxylation sequence.
Angew. Chem. Int. Ed. Engl. 45 , 1900, (2006)
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Ruthenium catalysed cross metathesis with fluorinated olefins.
Chem. Commun. (Camb.) , 1692, (2001) The E-selective cross metathesis (CM) of fluorinated olefins with various functionalised alkenes in good to excellent yields is reported. |
| Dichloro(1,3-dimesityl-2-imidazolidinylidene)(2-isopropoxybenzylidene)ruthenium |
| Hoveyda-Grubbs II |
| Grubbs-Hoveyda second generationpre-catalyst |
| (1,3-Dimesityl-2-imidazolidinylidene)(2-isopropoxybenzylidene)ruthenium(2+) dichloride |
| Ruthenium(2+), [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[2-(1-methylethoxy)phenyl]methylene]-, chloride (1:2) |
| Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy)phenyl]methylene]- |
| Hoveyda-Grubbs catalyst second-generation catalyst |
| Hoveyda-Grubbs Catalyst 2nd Generation |
| MFCD03701614 |
| HOVEYDA-GRUBBS 2ND GENERATION |
| IHMes-o-isopropoxybenzylidene-ruthenium dichloride |
| (1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium |