Phosphonic acid,P-(diazomethyl)-, dimethyl ester

Modify Date: 2025-08-22 10:27:27

Phosphonic acid,P-(diazomethyl)-, dimethyl ester Structure
Phosphonic acid,P-(diazomethyl)-, dimethyl ester structure
Common Name Phosphonic acid,P-(diazomethyl)-, dimethyl ester
CAS Number 27491-70-9 Molecular Weight 150.07300
Density N/A Boiling Point N/A
Molecular Formula C3H7N2O3P Melting Point N/A
MSDS N/A Flash Point N/A

 Names

Name diazo(dimethoxyphosphoryl)methane
Synonym More Synonyms

 Chemical & Physical Properties

Molecular Formula C3H7N2O3P
Molecular Weight 150.07300
Exact Mass 150.01900
PSA 82.73000
LogP 0.81146
InChIKey QUZMIAJIRIZFQN-UHFFFAOYSA-N
SMILES COP(=O)(C=[N+]=[N-])OC
Storage condition -20℃

 Synthetic Route

~46%

Phosphonic acid,P-(diazomethyl)-, dimethyl ester Structure

Phosphonic acid...

CAS#:27491-70-9

Literature: Nahrwold, Markus; Bogner, Tobias; Eissler, Stefan; Verma, Spart; Sewald, Norbert Organic Letters, 2010 , vol. 12, # 5 p. 1064 - 1067

~91%

Phosphonic acid,P-(diazomethyl)-, dimethyl ester Structure

Phosphonic acid...

CAS#:27491-70-9

Literature: Ohira, Susumu Synthetic Communications, 1989 , vol. 19, # 3and4 p. 561 - 564

~%

Phosphonic acid,P-(diazomethyl)-, dimethyl ester Structure

Phosphonic acid...

CAS#:27491-70-9

Literature: Brown, Dean G.; Velthuisen, Emil J.; Commerford, Jessica R.; Brisbois, Ronald G.; Hoye, Thomas R. Journal of Organic Chemistry, 1996 , vol. 61, # 7 p. 2540 - 2541

~%

Phosphonic acid,P-(diazomethyl)-, dimethyl ester Structure

Phosphonic acid...

CAS#:27491-70-9

Literature: Brown, Dean G.; Velthuisen, Emil J.; Commerford, Jessica R.; Brisbois, Ronald G.; Hoye, Thomas R. Journal of Organic Chemistry, 1996 , vol. 61, # 7 p. 2540 - 2541

 Synonyms

diazomethyl-phosphonic acid dimethyl ester
Gilbert-Seyferth reagent
O,O-dimethyl diazomethylphosphonate
Methyl diazomethylphosphonate
Dimethylphosphonodiazomethane
Seyferth-Gilbert reagent
Reagents,Seyferth-Gilbert
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