SLAP N-Bn Pip Reagent

Modify Date: 2024-04-06 16:23:21

SLAP N-Bn Pip Reagent Structure
SLAP N-Bn Pip Reagent structure
Common Name SLAP N-Bn Pip Reagent
CAS Number 1908469-38-4 Molecular Weight 236.44
Density 0.9366g/mL Boiling Point 265.4±20.0 °C at 760 mmHg
Molecular Formula C13H24N2Si Melting Point N/A
MSDS N/A Flash Point 114.3±21.8 °C

 Use of SLAP N-Bn Pip Reagent


Description Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, formN-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)2dtbbpy]PF6(747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with theBode Research Groupand provides a tin-free alternative toSnAP(tin amine protocol) reagents for piperazine synthesis.

 Names

Name SLAP N-Bn Pip Reagent
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9366g/mL
Boiling Point 265.4±20.0 °C at 760 mmHg
Molecular Formula C13H24N2Si
Molecular Weight 236.44
Flash Point 114.3±21.8 °C
Exact Mass 236.170868
LogP 2.65
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.508

 Synonyms

N1-Benzyl-N1-((trimethylsilyl)methyl)ethane-1,2-diamine