(R)-(+)-4-DIMETHYLAMINOPYRINDINYL(PENTAPHENYLCYCLOPENTADIENYL)IRON

Modify Date: 2024-02-01 23:29:35

(R)-(+)-4-DIMETHYLAMINOPYRINDINYL(PENTAPHENYLCYCLOPENTADIENYL)IRON Structure
(R)-(+)-4-DIMETHYLAMINOPYRINDINYL(PENTAPHENYLCYCLOPENTADIENYL)IRON structure
Common Name (R)-(+)-4-DIMETHYLAMINOPYRINDINYL(PENTAPHENYLCYCLOPENTADIENYL)IRON
CAS Number 187596-69-6 Molecular Weight 657.60200
Density N/A Boiling Point N/A
Molecular Formula C45H33FeN2 Melting Point 231-234ºC
MSDS N/A Flash Point N/A

 Names

Name 5H-Cyclopenta[b]pyridine-4a,7a-diyl-5,6,7-triylidene, 4-(dimethyl amino)-, compd. with 1,2,3,4,5-pentaphenyl-1,2,3,4,5-cyclopentane pentayl, iron salt (1:1:1)
Synonym More Synonyms

 Chemical & Physical Properties

Melting Point 231-234ºC
Molecular Formula C45H33FeN2
Molecular Weight 657.60200
Exact Mass 657.19900
PSA 16.13000
LogP 8.29560

 MSDS


Section 1: Product Identification
Chemical Name:(S)-(-)-4-Dimethylaminopyrindinyl(pentaphenylcyclopentadienyl)iron, min. 98% (S)-C5Ph5-DMAP
CAS Registry Number:187596-69-6
Formula:C45H36FeN2
EINECS Number:none
Chemical Family:Organic amine
Synonym:none

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound187596-69-6100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, and eyes. May be irritating to the respiratory tract. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, eyes
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:May be irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information available on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin and eyes. May be irritating to the respiratory tract.
The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards
Chronic Health Affects:
may be present.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:none
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry area away from heat and direct sunlight.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:purple xtl
Molecular Weight:660.6
Melting Point:231-234°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents and halogens
Decomposition Products:carbon monoxide, carbon dioxide, organic fumes and iron oxide.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to federal, state, and local regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Synonyms

(-)(C5Ph5)Fe(C8H5N(dimethylamino))
[(4A,5,6,7,7A-H)-4-(DIMETHYLAMINO)-1H-1-PYRIDIN-5-YL][1,2,3,4,5-H)-1,2,3,4,5-PENTA-PHENYL-2,4-CYCLOPENTADIEN-1-YL]IRON
(-)-(C5Ph5)FeC5H3NC3H(dimethylamino)
(R)-C5PH5-DMAP
(S)-C5PH5-DMAP
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