Bis(1-adamantyl)phosphinic chloride

Modify Date: 2024-01-11 20:25:15

Bis(1-adamantyl)phosphinic chloride Structure
Bis(1-adamantyl)phosphinic chloride structure
Common Name Bis(1-adamantyl)phosphinic chloride
CAS Number 126683-99-6 Molecular Weight 352.878
Density 1.2±0.1 g/cm3 Boiling Point 498.0±12.0 °C at 760 mmHg
Molecular Formula C20H30ClOP Melting Point 214ºC
MSDS N/A Flash Point 255.0±19.6 °C

 Names

Name 1-[1-adamantyl(chloro)phosphoryl]adamantane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 498.0±12.0 °C at 760 mmHg
Melting Point 214ºC
Molecular Formula C20H30ClOP
Molecular Weight 352.878
Flash Point 255.0±19.6 °C
Exact Mass 352.172272
PSA 26.88000
LogP 5.01
Appearance of Characters crystal | white
Vapour Pressure 0.0±1.2 mmHg at 25°C
Index of Refraction 1.570

 MSDS


Section 1: Product Identification
Chemical Name:Di-1-adamantylphosphinic chloride, 98%
CAS Registry Number:126683-99-6
Formula:(C10H15)2POCl
EINECS Number:none
Chemical Family:organophosphine ligand
Synonym:Di-1-adamantylchlorophosphane

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound126683-99-6100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Inhalation, skin, eyes.
Eye Contact:Dust causes moderate to severe irritation of the eyes.
Skin Contact:Causes moderate to severe irritation of the skin. May cause redness, itching and pain.
Inhalation:Dust is irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No specific information is available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam.
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store the material in a cool, dry place in a tightly sealed container. Handle under a dry atmosphere.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white xtl.
Molecular Weight:352.88
Melting Point:214°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:not determined
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:moisture sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents and halogens
Decomposition Products:carbon monoxide, carbon dioxide, hydrogen chloride, organic fumes and phosphorus pentoxide.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to federal, state, and local regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

HS Code 2903890090

 Synthetic Route

~93%

Bis(1-adamantyl)phosphinic chloride Structure

Bis(1-adamantyl...

CAS#:126683-99-6

Literature: No, B. I.; Zotov, Yu. L.; Karev, V. N. J. Gen. Chem. USSR (Engl. Transl.), 1990 , vol. 60, # 8.1 p. 1795 - 1799,1603 - 1606

~87%

Bis(1-adamantyl)phosphinic chloride Structure

Bis(1-adamantyl...

CAS#:126683-99-6

Literature: Yurchenko, R. I.; Peresypkina, L. P.; Miroshnichenko, V. V.; Yurchenko, A. G. Russian Journal of General Chemistry, 1993 , vol. 63, # 7.1 p. 1072 - 1076 Zhurnal Obshchei Khimii, 1993 , vol. 63, # 7 p. 1534 - 1539

~95%

Bis(1-adamantyl)phosphinic chloride Structure

Bis(1-adamantyl...

CAS#:126683-99-6

Literature: Beller, Matthias; Ehrentraut, Andreas; Ehrentraut, Wilhelm Hubert; Ehrentraut, Theresia Elisabeth; Fuhrmann, Christa; Zapf, Alexander Patent: US2004/68131 A1, 2004 ;

~87%

Bis(1-adamantyl)phosphinic chloride Structure

Bis(1-adamantyl...

CAS#:126683-99-6

Literature: Yurchenko, R. I.; Peresypkina, L. P. J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 10.2 p. 2389 - 2390,1971

~44%

Bis(1-adamantyl)phosphinic chloride Structure

Bis(1-adamantyl...

CAS#:126683-99-6

Literature: Yurchenko, A. G.; Fedorenko, T. V.; Titova, M. I.; Yurchenko, R. I.; Voitsekhovskaya, O. M. J. Gen. Chem. USSR (Engl. Transl.), 1989 , vol. 59, # 10.1 p. 2212 - 2217,1982 - 1986

 Customs

HS Code 2903890090
Summary 2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

 Synonyms

Diadamantan-1-ylphosphinic chloride
Di-1-adamantylphosphinsaeurechlorid
Phosphinic chloride, P,P-ditricyclo[3.3.1.1]dec-1-yl-
DI-1-ADAMANTYLPHOSPHINIC CHLORIDE