Copper quinolate

Modify Date: 2024-01-02 07:29:44

Copper quinolate Structure
Copper quinolate structure
Common Name Copper quinolate
CAS Number 10380-28-6 Molecular Weight 351.846
Density 1,68 g/cm3 Boiling Point 267ºC at 760 mmHg
Molecular Formula C18H12CuN2O2 Melting Point 240 °C (dec.)(lit.)
MSDS N/A Flash Point 143.1ºC

 Names

Name oxine-copper
Synonym More Synonyms

 Chemical & Physical Properties

Density 1,68 g/cm3
Boiling Point 267ºC at 760 mmHg
Melting Point 240 °C (dec.)(lit.)
Molecular Formula C18H12CuN2O2
Molecular Weight 351.846
Flash Point 143.1ºC
Exact Mass 351.019470
PSA 44.24000
LogP 4.15330

 MSDS


Section 1. Chemical Product and Company Identification
8-Hydroxyquinoline, Copper Salt
Common Name/
Trade Name
Manufacturer
Commercial Name(s)
Synonym
Chemical Name
Chemical Family
8-Hydroxyquinoline, Copper Salt

Section 4. First Aid Measures
Eye ContactCheck for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Get medical attention.
Skin ContactIn case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove
contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention.
Serious Skin ContactWash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical
attention.
InhalationIf inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious InhalationNot available.
IngestionDo NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if
symptoms appear.
Serious IngestionNot available.

Section 5. Fire and Explosion Data
Flammability of the Product May be combustible at high temperature.
Auto-Ignition Temperature Not available.
Flash PointsNot available.
Flammable LimitsNot available.
Products of CombustionThese products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
Fire Hazards in Presence of Slightly flammable to flammable in presence of heat.
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
of Various SubstancesRisks of explosion of the product in presence of static discharge: Not available.
Fire Fighting MediaSMALL FIRE: Use DRY chemical powder.
and InstructionsLARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks onNot available.
Fire Hazards
Special Remarks on Explosion Not available.
Hazards

Section 6. Accidental Release Measures
Small SpillUse appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large SpillUse a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water
on the contaminated surface and allow to evacuate through the sanitary system.
8-Hydroxyquinoline, Copper Salt

Section 7. Handling and Storage
PrecautionsKeep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not
ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable
respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes.
StorageKeep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 8°C (46.4°F).
Refrigerate.

Section 8. Exposure Controls/Personal Protection
Engineering ControlsUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal ProtectionSplash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
a Large Spillto avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure LimitsNot available.

Section 9. Physical and Chemical Properties
Physical state and appearance Solid. (crystalline powder)OdorNot available.
Not available.
Taste
Molecular Weight351.85 g/mole
greenish-yellow
Color
Not applicable.
pH (1% soln/water)
Boiling PointNot available.
Melting Point>200°C (392°F)
Critical TemperatureNot available.
Specific GravityNot available.
Not applicable.
Vapor Pressure
Vapor DensityNot available.
Not available.
Volatility
Odor ThresholdNot available.
Water/Oil Dist. Coeff.Not available.
Ionicity (in Water)Not available.
Dispersion PropertiesNot available.
SolubilityInsoluble in cold water, hot water.

Section 10. Stability and Reactivity Data
StabilityThe product is stable.
Instability TemperatureNot available.
Conditions of InstabilityExcess heat, excess dust generation
Incompatibility with variousNot available.
substances
CorrosivityNot available.
8-Hydroxyquinoline, Copper Salt
Special Remarks onNot available.
Reactivity
Special Remarks onNot available.
Corrosivity
PolymerizationWill not occur.

Section 11. Toxicological Information
Routes of EntryInhalation. Ingestion.
Toxicity to AnimalsAcute oral toxicity (LD50): 3940 mg/kg [Mouse].
Acute dermal toxicity (LD50): >2000 mg/kg [Rabbit].
Chronic Effects on Humans MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast.
Other Toxic Effects onHazardous in case of inhalation.
HumansSlightly hazardous in case of skin contact (irritant, permeator), of ingestion.
Special Remarks onLethal Dose/Conc 50% Kill:
Toxicity to AnimalsLC50 [Rat] - Route: Inhalation; Dose: 820 mg/kg.
*Please Note that the time period for testing was not indicated by the Registery of Toxic Effects of Chemial
Substances (RTECS).
Special Remarks onMay affect genetic material and may cause cancer based on animal data. No human data found.
Chronic Effects on Humans
Special Remarks on otherAcute Potential Health Effects:
Toxic Effects on HumansSkin: May cause skin irritation. It may be absorbed through the skin.
Eye: Dust may cause eye irritation.
Inhalation: Dust may cause respiratory tract irritation. May be harmful if inhaled.
Ingestion: May affect behavior (somnolence - general depressed activity), gastrointestinal tract (irritation,
diarrhea, hypermotility), repiratory system (dyspnea), nervous system
Chronic Potential Health Effects: liver (hepatitis), urinary system, spleen, metabolism (weight loss), blood.

Section 12. Ecological Information
EcotoxicityNot available.
BOD5 and CODNot available.
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
Products of Biodegradation
arise.
The products of degradation are less toxic than the product itself.
Toxicity of the Products
of Biodegradation
Special Remarks on theNot available.
Products of Biodegradation

Section 13. Disposal Considerations
Waste DisposalWaste must be disposed of in accordance with federal, state and local environmental
control regulations.
8-Hydroxyquinoline, Copper Salt

Section 14. Transport Information
DOT ClassificationNot a DOT controlled material (United States).
IdentificationNot applicable.
Not applicable.
Special Provisions for
Transport
DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
TSCA 8(b) inventory: 8-Hydroxyquinoline, Copper Salt
Federal and State
Regulations
CaliforniaCalifornia prop. 65: This product contains the following ingredients for which the State of California has found
to cause cancer which would require a warning under the statute: No products were found.
Proposition 65
Warnings
California prop. 65: This product contains the following ingredients for which the State of California has found
to cause birth defects which would require a warning under the statute: No products were found.
Other RegulationsEINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No.
233-841-9).
Canada: Listed on Canadian Non-Domestic Substance List (NDSL).
China: Listed on National Inventory.
Japan: Listed on National Inventory (ENCS).
Korea: Listed on National Inventory (KECI).
Philippines: Listed on National Inventory (PICCS).
Australia: Listed on AICS.
WHMIS (Canada) CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC).
Other Classifications
DSCL (EEC)
R20- Harmful by inhalation.S22- Do not breathe dust.
Health Hazard
HMIS (U.S.A.)2 National Fire Protection
1 Flammability
1 Association (U.S.A.)
Fire Hazard
2 0 Reactivity
Health
Reactivity
0
Specific hazard
Personal Protection
E
WHMIS (Canada)
(Pictograms)
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
8-Hydroxyquinoline, Copper Salt
ADR (Europe)
(Pictograms)
Protective Equipment
Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VC5250000
CHEMICAL NAME :
8-Quinolinol, copper (II) chelate
CAS REGISTRY NUMBER :
10380-28-6
LAST UPDATED :
199710
DATA ITEMS CITED :
20
MOLECULAR FORMULA :
C18-H12-Cu-N2-O2
MOLECULAR WEIGHT :
351.86
WISWESSER LINE NOTATION :
T66 BNJ JO 2-CU-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
9930 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - hypermotility, diarrhea
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
820 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
22 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3940 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - hypermotility, diarrhea
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
67 mg/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - dyspnea
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
48 gm/kg/30D-I
TOXIC EFFECTS :
Liver - liver function tests impaired Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
87600 mg/kg/2Y-C
TOXIC EFFECTS :
Liver - other changes Kidney, Ureter, Bladder - other changes Endocrine - changes in spleen weight
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
21840 mg/kg/13W-C
TOXIC EFFECTS :
Liver - other changes Endocrine - changes in spleen weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
54600 mg/kg/2Y-C
TOXIC EFFECTS :
Gastrointestinal - malabsorption Liver - hepatitis (hepatocellular necrosis), diffuse Liver - change in gall bladder structure or function
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
156 mg/kg/39W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
5 ug/plate
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 116,185,1983 *** REVIEWS *** IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 15,103,1977 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 15,103,1977 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 82785 No. of Facilities: 28 (estimated) No. of Industries: 3 No. of Occupations: 7 No. of Employees: 792 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 82785 No. of Facilities: 33 (estimated) No. of Industries: 3 No. of Occupations: 3 No. of Employees: 406 (estimated)

 Safety Information

Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases S26-S36
RIDADR UN 3077 9/PG 3
WGK Germany 3
RTECS VC5250000
HS Code 2933499090

 Synthetic Route

~82%

Copper quinolate Structure

Copper quinolate

CAS#:10380-28-6

Literature: Journal of Solid State Chemistry, , vol. 106, p. 451 - 460

~%

Copper quinolate Structure

Copper quinolate

CAS#:10380-28-6

Literature: Kinetics and Catalysis, , vol. 26, p. 50 - 57 Kinetika i Kataliz, , vol. 26, p. 61 - 68

~28%

Copper quinolate Structure

Copper quinolate

CAS#:10380-28-6

Literature: Russian Journal of Physical Chemistry, , vol. 54, # 12 p. 1784 - 1786 Zhurnal Fizicheskoi Khimii, , vol. 54, p. 3118 - 3122

~%

Copper quinolate Structure

Copper quinolate

CAS#:10380-28-6

Literature: Helvetica Chimica Acta, , vol. 8, p. 596 - 602

 Customs

HS Code 2933499090
Summary 2933499090. other compounds containing in the structure a quinoline or isoquinoline ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

cupric 8-quinolinoxide
QUINONDO
Copper(2+) di(8-quinolinolate)
8-Hydroxyquinoline copper complex
copper 8-quinolinolate
Copper 8-hydroxyquinolinate
Dokirin
8-Hydroxyquinoline Copper Salt
MFCD00067392
Oxine-Copper
Copper quinolate
Dokivin
8-Quinolinol, copper(2+) salt (2:1)
Milmer 1
Culinate
Copper-8
(8-hydroxy quinolinato)2Cu
Fruitdo
bis(quinolin-8-olato-O,N)copper(II)
Cunilate
Copper(II) Bis(8-hydroxyquinolinate)
[Cu(8-HQ)2]
Copper(2+) diquinolin-8-olate
Copper-8-hydroxyquinoline
bis(8-hydroxyquinolato)copper(II)
Cupric 8-quinolinolate
copper(II) bis(quinolin-8-olate)
Bis(8-quinolinolato)copper(II)
Milmer
bis(8-quinolinolato-κN1,κO8)copper
EINECS 233-841-9
bis(8-hydroxyquinolinato)copper(II)
bioquin1
Copper-8-quinolinolate
oxine-Cu
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