54012-92-9

54012-92-9 structure
54012-92-9 structure
  • Name: 1,2,3,4-Tetrahydroquinolin-8-amine
  • Chemical Name: 8-amino-1,2,3,4-tetrahydroquinoline
  • CAS Number: 54012-92-9
  • Molecular Formula: C9H12N2
  • Molecular Weight: 148.20500
  • Create Date: 2018-12-05 18:08:44
  • Modify Date: 2024-01-02 18:03:05

Name 8-amino-1,2,3,4-tetrahydroquinoline
Synonyms 1,2,3,4-tetrahydro-8-quinolinamin
1,2,3,4-Tetrahydro-8-quinolinamine.
8-Amino-1,2,3,4-tetrahydroquinoline,pract.
1,2,3,4-Tetrahydroquinoline-8-amine
1,2,3,4-tetrahydro-quinolin-8-ylamine
8-amino-1-2-3-4-tetrahydroquinoline*grade iii
1,2,3,4-tetrahydroquinolin-8-amine
8-Quinolinamine,1,2,3,4-tetrahydro
Density 1.101g/cm3
Boiling Point 316ºC at 760mmHg
Molecular Formula C9H12N2
Molecular Weight 148.20500
Flash Point 169.3ºC
Exact Mass 148.10000
PSA 38.05000
LogP 2.34610
Index of Refraction 1.599
Storage condition 2-8°C
Name: 8-Amino-1 2 3 4-Tetrahydroquinoline (Pract) 97% (Titr.) Material Safety Data Sheet
Synonym: 1,2,3,4-Tetrahydro-8-Quinolinamine
CAS: 54012-92-9
Section 1 - Chemical Product MSDS Name:8-Amino-1 2 3 4-Tetrahydroquinoline (Pract) 97% (Titr.) Material Safety Data Sheet
Synonym:1,2,3,4-Tetrahydro-8-Quinolinamine

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
54012-92-9 8-Amino-1,2,3,4-Tetrahydroquinoline 97 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 54012-92-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: clear almost colorless
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H12N2
Molecular Weight: 148.21

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 54012-92-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
8-Amino-1,2,3,4-Tetrahydroquinoline - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 54012-92-9: No information available.
Canada
CAS# 54012-92-9 is listed on Canada's NDSL List.
CAS# 54012-92-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 54012-92-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
HS Code 2933499090

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54012-92-9 structure

54012-92-9

Literature: Ren, Dong; He, Lin; Yu, Lei; Ding, Ran-Sheng; Liu, Yong-Mei; Cao, Yong; He, He-Yong; Fan, Kang-Nian Journal of the American Chemical Society, 2012 , vol. 134, # 42 p. 17592 - 17598,7

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54012-92-9

Literature: Murahashi; Imada; Hirai Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 9 p. 2968 - 2976

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54012-92-9 structure

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Literature: US2001/53783 A1, ;

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54012-92-9 structure

54012-92-9

Literature: Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2721 - 2728

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54012-92-9 structure

54012-92-9

Literature: Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2721 - 2728

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54012-92-9 structure

54012-92-9

Literature: Journal of the American Chemical Society, , vol. 74, p. 2953,2957
HS Code 2933499090
Summary 2933499090. other compounds containing in the structure a quinoline or isoquinoline ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%