N,N'-Diethylhydrazine dihydrochloride

Names

[ Name ]:
N,N'-Diethylhydrazine dihydrochloride

[Synonym ]:
1,2-Diethylhydrazine dihydrochloride
EtHNNHEt*2HCl
diethylhydrazine dihydrochloride
1,2-Diethylhydrazine 2HCl
MFCD00012523
N,N'-Diaethyl-hydrazin,Dihydrochlorid
UNII-X3O3IWE4TG
Hydrazine,1,2-diethyl-,dihydrochloride
N,N'-diethylhydrazine dihydrochloride

Chemical & Physical Properties

[ Boiling Point ]:
84.7ºC at 760 mmHg

[ Melting Point ]:
169ºC (dec.)(lit.)

[ Molecular Formula ]:
C₄H₁₄Cl₂N₂

[ Molecular Weight ]:
161.07300

[ Exact Mass ]:
160.05300

[ PSA ]:
24.06000

[ LogP ]:
2.50620

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MV2295000

CHEMICAL NAME :: Hydrazine, 1,2-diethyl-, dihydrochloride

CAS REGISTRY NUMBER :: 7699-31-2

LAST UPDATED :: 199806

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C4-H12-N2.2Cl-H

MOLECULAR WEIGHT :: 161.10

WISWESSER LINE NOTATION :: 2MM2 &GH 2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 50 mg/kg female 15 day(s) after conception

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Reproductive - Tumorigenic effects - transplacental tumorigenesis Brain and Coverings - tumors

MUTATION DATA

TEST SYSTEM :: Insect - Drosophila melanogaster

DOSE/DURATION :: 500 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 395,229,1997

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H335-H350

[ Precautionary Statements ]:
P201-P261-P280-P305 + P351 + P338-P308 + P313

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R25;R45

[ Safety Phrases ]:
S45-S53

[ RIDADR ]:
UN 2811

[ WGK Germany ]:
3

[ RTECS ]:
MV2295000

[ Packaging Group ]:
III

[ HS Code ]:
2928000090

Customs

[ HS Code ]: 2928000090

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Aqueous N-heterocyclization of primary amines and hydrazines with dihalides: microwave-assisted syntheses of N-azacycloalkanes, isoindole, pyrazole, pyrazolidine, and phthalazine derivatives.

J. Org. Chem. 71 , 135-141, (2006)

[reactions: see text] The synthesis of nitrogen-containing heterocycles from alkyl dihalides (ditosylates) and primary amines and hydrazines via a simple and efficient cyclocondensation in an alkaline...