N,N'-DI-TERT-BUTYLCARBODIIMIDE

Names

[ CAS No. ]:
691-24-7

[ Name ]:
N,N'-DI-TERT-BUTYLCARBODIIMIDE

[Synonym ]:
EINECS 211-719-6
2-Propanamine, N,N'-methanetetraylbis[2-methyl-
N,N'-DI-TERT-BUTYLCARBODIIMIDE
MFCD00010231
N,N'-Bis(2-methyl-2-propanyl)carbodiimide
2-Propanamine, N-[(1,1-dimethylethyl)carbonimidoyl]-2-methyl-
tBuN=C=NtBu
Di-tert-butylcarbodiimide

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
160.6±0.0 °C at 760 mmHg

[ Melting Point ]:
35ºC

[ Molecular Formula ]:
C₉H₁₈N₂

[ Molecular Weight ]:
154.253

[ Flash Point ]:
35.0±0.0 °C

[ Exact Mass ]:
154.147003

[ PSA ]:
24.72000

[ LogP ]:
3.88

[ Vapour Pressure ]:
3.1±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.434

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
26-36

[ RIDADR ]:
UN 1993 3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2921199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2921199090

[ Summary ]:
2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Highly atom efficient guanylation of both aromatic and secondary amines catalyzed by simple lanthanide amides.

J. Org. Chem. 72 , 6763, (2007)

It is demonstrated that the cyclopentadienyl-free simple lanthanide amides [(Me(3)Si)(2)N](3)Ln(mu-Cl)Li(THF)(3)(Ln = La, Sm, Eu, Y, Yb) and Ln[N(SiMe(3))(2)]3 (Ln = Y, Yb) are highly efficient cataly...