(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)

Names

[ Name ]:
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)

[Synonym ]:
ir(acac)(cod)
(ACETYLACETONATO)(1,5-CYCLOOCTADIENE)IRIDIUM(I)
(acetylacetonato)(1,5-cyclopentadienyl)iridium(I)
acetylacetonate-1,5-cyclooctadiene iridium I
MFCD08273779
acetylacetonate-1,5-cyclooctadieneiridium
(1,5-cyclooctadiene)(2,4-pentanedionato)iridium
1,5-CYCLOOCTADIENE(ACETYLACETONATO)IRIDIUM (I)
1,5-CYCLOOKTADIENE(ACETYLACETONATO)IRIDIUM(I)
[Ir(cod)acac]
Ir(acetylacetonate)(cycloocta-1,5-diene)
[Ir(acetylacetonate)(1,5-cyclooctadiene)]
IRIDIUM PENTANEDIONATE-CYCLOOCTADIENE COMPLEX

Chemical & Physical Properties

[ Boiling Point ]:
152ºC at 760 mmHg

[ Melting Point ]:
145-150ºC (dec.)

[ Molecular Formula ]:
C₁₃H₁₉IrO

[ Molecular Weight ]:
383.50600

[ Flash Point ]:
30ºC

[ Exact Mass ]:
384.10700

[ PSA ]:
17.07000

[ LogP ]:
3.40610

[ Appearance of Characters ]:
crystal | yellow

[ Vapour Pressure ]:
4.56mmHg at 25°C

[ Water Solubility ]:
Insoluble in water.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: NO3615000

CHEMICAL NAME :: Iridium, ((1,2,5,6-eta)-1,5-cyclooctadiene)(2,4-pentanedionato -O,O')-

CAS REGISTRY NUMBER :: 12154-84-6

LAST UPDATED :: 198806

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C13-H19-Ir-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 47 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CBINA8 Chemico-Biological Interactions. (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1969- Volume(issue)/page/year: 45,1,1983

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
NO3615000

Synthetic Route

Click to get detail synthetic route

Articles

Antitumor effects of rhodium(I), iridium(I) and ruthenium(II) complexes in comparison with cis-dichlorodiammino platinum(II) in mice bearing Lewis lung carcinoma.

Chem. Biol. Interact. 45(1) , 1-6, (1983)

The effects of square planar rhodium, [RhacacCOD]o and iridium, [IracacCOD]o complexes and of octahedral ruthenium, [cis-RuCl2 (DMSO)4]o complex have been examined in comparison with cis-dichlorodiamm...