pipsyl chloride

Names

[ CAS No. ]:
98-61-3

[ Name ]:
pipsyl chloride

[Synonym ]:
pipsyl chloride
EINECS 202-686-9
Benzenesulfonyl chloride, p-iodo-
Iodobenzene-p-sulfonyl chloride
4-Iodo benzenesulfonyl chloride
4-Iodo-benzenesulfonyl chloride
Benzenesulfonyl chloride, 4-iodo-
p-Iodophenyl Sulfonyl Chloride
p-Iodobenzenesulfonyl chloride
p-Iodophenylsulfonyl chloride
MFCD00007441
4-Iodobenzenesulfonyl chloride

Chemical & Physical Properties

[ Density]:
2.0±0.1 g/cm3

[ Boiling Point ]:
319.1±25.0 °C at 760 mmHg

[ Melting Point ]:
80-82 °C(lit.)

[ Molecular Formula ]:
C₆H₄ClIO₂S

[ Molecular Weight ]:
302.517

[ Flash Point ]:
146.8±23.2 °C

[ Exact Mass ]:
301.866516

[ PSA ]:
42.52000

[ LogP ]:
3.28

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.639

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S27-S36/37/39-S45-S28A

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
29049020

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Synthesis and Photophysical Studies of Calixarene-Based Alkynylplatinum(II) Terpyridine Complexes with Various Receptor Sites for Colorimetric and Luminescence Sensing of Anions.

Chemistry 22 , 3738-49, (2016)

A series of mononuclear and dinuclear platinum(II) terpyridine complexes with amide-, sulfonamide-, and urea-containing ligands (1-9) has been successfully designed and synthesized, and their photophy...

Circular dichroism study of thyroxine-binding globulin derivatized with p-iodophenylsulfonyl chloride.

Int. J. Biochem. 16(5) , 575-7, (1984)

The reaction of iodobenzene-p-sulphonyl chloride (pipsyl chloride) with certain amino acids and peptides, and with insulin.

Biochem. J. 102(3) , 815-24, (1967)

1. A system of separation using buffered Celite columns is described that enables the pipsyl derivatives of most of the common amino acids to be separated. 2. The reaction of pipsyl chloride with seve...