2-Chlorothiophene

Names

[ CAS No. ]:
96-43-5

[ Name ]:
2-Chlorothiophene

[Synonym ]:
ChloroThiophene
thien-2-yl chloride
EINECS 202-505-3
2-Chloro thiophene
2,3,4,5-Chlorothiophene
2-thienyl chloride
2-Chlorothiphene
2-thiophenyl chloride
2-Chlorothiophene
THIENYL CHLORIDE
Thiophene, 2-chloro-
2-chloro-thiophene
2-Chlorothiophenato
2-chloro-thiophen
thiophene,2-chloro
MFCD00005421

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
128.3±0.0 °C at 760 mmHg

[ Melting Point ]:
-71.9 °C

[ Molecular Formula ]:
C₄H₃ClS

[ Molecular Weight ]:
118.585

[ Flash Point ]:
22.8±0.0 °C

[ Exact Mass ]:
117.964401

[ PSA ]:
28.24000

[ LogP ]:
2.54

[ Vapour Pressure ]:
13.0±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.564

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
INSOLUBLE

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S16-S26-S36-S45-S38-S36/37/39-S28B

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
XM8575000

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
29349990

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 29349990

Articles

Photodissociation dynamics of halogenated thiophenes at 235 nm: a resonance enhanced multiphoton ionization-time-of-flight (REMPI-TOF) study.

J. Phys. Chem. A 116(44) , 10656-67, (2012)

The photodissociation dynamics of halogen-substituted thiophenes, namely, 2-chlorothiophene and 2-bromo-5-chlorothiophene, has been studied in a supersonic molecular beam around 235 nm, using resonanc...

Mechanistic studies on the Pd-catalyzed direct C-H arylation of 2-substituted thiophene derivatives with arylpalladium bipyridyl complexes.

Chem. Asian J. 7(6) , 1256-60, (2012)

Direct C-H phenylation of 2-ethylthiophene and 2-chlorothiophene with PhPdI(bipy) complex to form either the corresponding 4-phenyl or 5-phenylthiophene derivative is studied under stoichiometric cond...