Ethyl 4-nitrocinnamate

Names

[ CAS No. ]:
953-26-4

[ Name ]:
Ethyl 4-nitrocinnamate

[Synonym ]:
ETHYL-P-NITROCINNAMATE
p-nitro-cinnamicaciethylester
MFCD00007380
4-NITROCINNAMIC ACID ETHYL ESTER
ETHYL 4-NITROCINNNAMATE
Cinnamic acid,p-nitro-,ethyl ester
EINECS 213-463-0
4-Nitrozimtsaeure-ethylester
RARECHEM AL BI 0194
4-nitro ethyl cinnamate

Chemical & Physical Properties

[ Density]:
1.237g/cm3

[ Boiling Point ]:
326.6ºC at 760mmHg

[ Melting Point ]:
138-140 °C(lit.)

[ Molecular Formula ]:
C₁₁H₁₁NO₄

[ Molecular Weight ]:
221.20900

[ Flash Point ]:
141ºC

[ Exact Mass ]:
221.06900

[ PSA ]:
72.12000

[ LogP ]:
2.69430

[ Index of Refraction ]:
1.582

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GE0353332

CHEMICAL NAME :: Cinnamic acid, p-nitro-, ethyl ester

CAS REGISTRY NUMBER :: 953-26-4

BEILSTEIN REFERENCE NO. :: 2052533

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C11-H11-N-O4

MOLECULAR WEIGHT :: 221.23

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 6,215,1954

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
GE0353332

[ HS Code ]:
29163900

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Reduction of Ethyl t-cinnamates by Samarium Diiodide Lin T-Y, et al.

J. Chin. Chem. Soc. 48(5) , 843--848, (2001)