4-Methoxycyclohexanecarboxylic acid

Names

[ Name ]:
4-Methoxycyclohexanecarboxylic acid

[Synonym ]:
4-methoxycyclohex-3-ene carbaldehyde
4-methoxy-cyclohex-3-ene-1-carbaldehyde
4-Formyl-methoxycyclohexen
4-methoxy-1-cyclohexanecarboxylic acid
MFCD00074992
1-Formyl-4-methoxy-cyclohexen-(3)
4-Methoxy-Cyclohexanecarboxylic Acid
4-methoxycyclohexylcarboxylic acid
4-Methoxy-cyclohex-3-encarbaldehyd

Chemical & Physical Properties

[ Density]:
1.09g/cm3

[ Boiling Point ]:
266.6ºC at 760mmHg

[ Melting Point ]:
55.5-58.5℃

[ Molecular Formula ]:
C₈H₁₄O₃

[ Molecular Weight ]:
158.19500

[ Flash Point ]:
105.3ºC

[ Exact Mass ]:
158.09400

[ PSA ]:
46.53000

[ LogP ]:
1.27620

[ Index of Refraction ]:
n20/D 1.4687(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-37/39

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2918990090

Synthetic Route

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Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Studies of Configuration. IV. The Rearrangement of Methoxycyclohexanecarboxylic Acids with Acetic Anhydride1. Noyce DS and Weingarten HI.

J. Am. Chem. Soc. 79(12) , 3098-3102, (1957)

Notes-Studies of Configuration. VI. cis-and trans-4-Methoxycyclohexanol. Noyce DS and Weingarten HI.

J. Org. Chem. 25(2) , 260-62, (1960)