P-TOLYL CHLOROFORMATE

Names

[ CAS No. ]:
937-62-2

[ Name ]:
P-TOLYL CHLOROFORMATE

[Synonym ]:
4-tolyl chloroformate
EINECS 213-332-8
p-Tolyl chloroforMate 5GR
1-chlorocarbonyloxy-4-methyl-benzene
Chloroformic acid p-tolyl ester
4-toluyl chloroformate
Chloroformic acid 4-methylphenyl ester
Phenyl chloroformate
4-Methylphenyl chloroformate
MFCD00013255

Chemical & Physical Properties

[ Density]:
1.234g/cm3

[ Boiling Point ]:
207.2ºC at 760mmHg

[ Molecular Formula ]:
C₈H₇ClO₂

[ Molecular Weight ]:
170.59300

[ Flash Point ]:
85.6ºC

[ Exact Mass ]:
170.01300

[ PSA ]:
26.30000

[ LogP ]:
2.73260

[ Appearance of Characters ]:
Liquid | Clear colorless

[ Index of Refraction ]:
n20/D 1.5099(lit.)

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H311-H314-H331

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R23/24/25

[ Safety Phrases ]:
26-27-36/37/39-45

[ RIDADR ]:
UN 3277 6.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Reaction of aryl chloroformates with dimethylformamide. Facile in situ synthesis of. alpha.-chlorocresols. Pattison VA, et al.

J. Org. Chem. 33(3) , 1084-87, (1968)