Bis(2,2,2-trifluoroethyl) Phosphite

Names

[ CAS No. ]:
92466-70-1

[ Name ]:
Bis(2,2,2-trifluoroethyl) Phosphite

[Synonym ]:
MFCD00063314
Bis(2,2,2-trifluoroethyl) phosphite

Chemical & Physical Properties

[ Density]:
1.545 g/mL at 25 °C(lit.)

[ Boiling Point ]:
43-44 °C2 mm Hg(lit.)

[ Molecular Formula ]:
C₄H₅F₆O₃P

[ Molecular Weight ]:
246.04500

[ Flash Point ]:
169 °F

[ Exact Mass ]:
245.98800

[ PSA ]:
59.00000

[ LogP ]:
2.53390

[ Appearance of Characters ]:
Liquid

[ Index of Refraction ]:
n20/D 1.332(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
23-26-28-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2920909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2920909090

[ Summary ]:
2920909090 esters of other inorganic acids of non-metals (excluding esters of hydrogen halides) and their salts; their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Improved synthesis of bis (2, 2, 2-trifluoroethyl) phosphorochloridate. Bowman RA, et al.

Organic Prep. and Proc. Int. 31(2) , 230-31, (1999)

Bis [2, 2, 2-trifluoroethyl] phosphite, a new reagent for synthesizing mono-and diesters of phosphorous acid. Gibbs DE and Larsen C.

Synthesis 5 , 410-13, (1984)