TERT-BUTYL(4-CHLOROBUTOXY)DIMETHYLSILANE

Names

[ Name ]:
TERT-BUTYL(4-CHLOROBUTOXY)DIMETHYLSILANE

[Synonym ]:
4-tert-butyldimethylsilyloxy-1-chlorobutane
MFCD00239391
Silane,(4-chlorobutoxy)(1,1-dimethylethyl)dimethyl
4-chlorobutyl t-butyldimethylsilyl ether
3-chlorobutanol-TBS ether
tert-butyl-(4-chlorobutoxy)dimethylsilane
1-(tert-butyldimethylsilyloxy)-4-chloro-butane

Chemical & Physical Properties

[ Density]:
0.87 g/mL at 25ºC(lit.)

[ Boiling Point ]:
201ºC(lit.)

[ Molecular Formula ]:
C₁₀H₂₃ClOSi

[ Molecular Weight ]:
222.82800

[ Flash Point ]:
179 °F

[ Exact Mass ]:
222.12100

[ PSA ]:
9.23000

[ LogP ]:
4.02720

[ Index of Refraction ]:
n20/D 1.439(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Samarium(II) iodide-mediated intramolecular conjugate additions of alpha,beta-unsaturated lactones.

J. Org. Chem. 67(11) , 3861-5, (2002)

Samarium(II) iodide, in the presence of catalytic amounts of nickel(II) iodide, has been used to promote intramolecular conjugate additions of alkyl halides onto alpha,beta-unsaturated lactones. This ...

Related Compounds

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