((4R,5R)-(+)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl] (diphenylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate (R,R)-[COD]Ir[Ph2P

[ Molecular Formula ]:
C₇₇H₅₈BF₂₄IrNO₃P

[ Molecular Weight ]:
1735.25000

[ Exact Mass ]:
1735.35000

[ PSA ]:
57.70000

[ LogP ]:
20.71320

Click to get detail MSDS

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

A New Class of Modular Phosphinite-Oxazoline Ligands: Ir-Catalyzed Enantioselective Hydrogenation of Alkenes We thank Dr. Martin Studer and Dr. Beno_t Pugin (Solvias AG, Basel) for fruitful discussions, and Prof. Kevin Burgess (Texas A&M University) for preprints of related unpublished work. Financial support by the Swiss National Science Foundation is gratefully acknowledged.

Angew. Chem. Int. Ed. Engl. 40 , 4445-4447, (2001)

Threonine-derived phosphinite-oxazoline ligands for the Ir-catalyzed enantioselective hydrogenation. Menges, F. and Pfaltz, A.

Adv. Synth. Catal. 344 , 40-44, (2002)

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