3-Bromothiophene

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
158.4±13.0 °C at 760 mmHg

[ Melting Point ]:
-10ºC

[ Molecular Formula ]:
C₄H₃BrS

[ Molecular Weight ]:
163.036

[ Flash Point ]:
56.7±0.0 °C

[ Exact Mass ]:
161.913879

[ PSA ]:
28.24000

[ LogP ]:
2.62

[ Vapour Pressure ]:
3.4±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.595

[ Storage condition ]:
0-6°C

[ Water Solubility ]:
IMMISCIBLE

Click to get detail MSDS

[ Symbol ]:

GHS02, GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H301-H310 + H330-H317-H319-H335-H411

[ Precautionary Statements ]:
P260-P273-P280-P284-P301 + P310-P302 + P350

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
N:Dangerous for the environment

[ Risk Phrases ]:
R10;R23/24/25;R36/37/38;R51/53

[ Safety Phrases ]:
S26-S36/37/39-S45-S61-S38-S28A-S16-S24/25-S23

[ RIDADR ]:
UN 2929 6.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
29349990

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Novel method of aromatic coupling between N-aryl methanesulfonamide and thiophene derivatives.

Org. Lett. 9 , 2553, (2007)

Oxidation of N-aromatic methanesulfonamides with iodobenzene diacetate in the presence of substituted thiophene promotes interesting coupling reactions in moderate to good yields.

Tetrahedron 63 , 4625, (2007)

A convenient synthesis of 3-alkylthiophenes. Pham CV, et al.

Synth. Commun. 16(6) , 689-696, (1986)

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