N-Benzyl-2-bromo-N-phenylbutanamide

Names

[ Name ]:
N-Benzyl-2-bromo-N-phenylbutanamide

[Synonym ]:
2-bromo-butyric acid-(N-benzyl-anilide)
2-bromo-N-phenyl-N-(phenylmethyl)-butanamide
N-benzyl-N-phenyl-2-bromobutanamide
2-Brom-buttersaeure-(N-benzyl-anilid)

Chemical & Physical Properties

[ Molecular Formula ]:
C₁₇H₁₈BrNO

[ Molecular Weight ]:
332.23500

[ Exact Mass ]:
331.05700

[ PSA ]:
20.31000

[ LogP ]:
4.39330

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H410

[ Precautionary Statements ]:
P273-P501

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ RIDADR ]:
UN 3077 9 / PGIII

[ HS Code ]:
2924299090

Synthetic Route

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Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Asymmetric nickel-catalyzed Negishi cross-couplings of secondary alpha-bromo amides with organozinc reagents.

J. Am. Chem. Soc. 127 , 4594, (2005)

A Ni/Pybox catalyst achieves the asymmetric cross-coupling of secondary alpha-bromo amides with organozinc reagents. The process tolerates a variety of functional groups and affords the desired produc...