Benzyl 2,2,2-trichloroacetimidate
Names
[ CAS No. ]:
81927-55-1
[ Name ]:
Benzyl 2,2,2-trichloroacetimidate
[Synonym ]:
Benzyl 2,2,2-trichloroethanimidate
Ethanimidic acid, 2,2,2-trichloro-, phenylmethyl ester
MFCD00000805
Benzyl 2,2,2-trichloroethanimidoate
BENZYL TRICHLOROACETIMIDATE
Chemical & Physical Properties
[ Density]:
1.4±0.1 g/cm3
[ Boiling Point ]:
319.5±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C9H8Cl3NO
[ Molecular Weight ]:
252.525
[ Flash Point ]:
107.0±30.1 °C
[ Exact Mass ]:
250.967148
[ PSA ]:
33.08000
[ LogP ]:
3.51
[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C
[ Index of Refraction ]:
1.550
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2925290090
Synthetic Route
Customs
[ HS Code ]: 2925290090
[ Summary ]:
2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%
Articles
Tetrahedron Asymmetry 3 , 1547, (1992)
Studies of novel cyclitols. A synthesis of 3'O, 4'O -dimethylfuniculosin. Williams DR, et al.
Tetrahedron Lett. 41(49) , 9397-9401, (2000)
The total synthesis of scytophycin C. Part 1: stereocontrolled synthesis of the C1? C32 protected seco acid. Paterson I, et al.
Tetrahedron 54(39) , 11935-11954, (1998)