Triisopropylsilyl trifluoromethanesulfonate

Names

[ Name ]:
Triisopropylsilyl trifluoromethanesulfonate

[Synonym ]:
tri(propan-2-yl)silyl trifluoromethanesulfonate
MFCD00009913
Triisopropylsilyl trifluoromethanesulfonate
Methanesulfonic acid, 1,1,1-trifluoro-, tris(1-methylethyl)silyl ester

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
252.9±35.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₀H₂₁F₃O₃SSi

[ Molecular Weight ]:
306.418

[ Flash Point ]:
106.8±25.9 °C

[ Exact Mass ]:
306.093262

[ PSA ]:
51.75000

[ LogP ]:
5.17

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.410

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Greene, T.W. Wuts, P.G.M.

Protective Groups in Organic Synthesis 2nd ed., New York , (1991), 74

Synlett , 435, (1993)

Tetrahedron 62 , 11371, (2006)