Boc-L-alaninal
Names
[ CAS No. ]:
79069-50-4
[ Name ]:
Boc-L-alaninal
[Synonym ]:
tert-Butyl [(2S)-1-oxopropan-2-yl]carbamate
Boc-L-alanine aldehyde
(S)-tert-Butyl (1-oxopropan-2-yl)carbamate
Carbamic acid, N-[(1S)-1-methyl-2-oxoethyl]-, 1,1-dimethylethyl ester
Boc-alaninal
Boc-Ala-Aldehyde
2-Methyl-2-propanyl (1-oxo-2-propanyl)carbamate
N-T-BOC-L-ALANINAL
2-Methyl-2-propanyl [(2S)-1-oxo-2-propanyl]carbamate
N-Boc-L-alaninal
Boc-L-alaninal
boc-L-alanine
Carbamic acid, N-(1-methyl-2-oxoethyl)-, 1,1-dimethylethyl ester
Boc-Ala-H
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
248.5±23.0 °C at 760 mmHg
[ Melting Point ]:
89 °C
[ Molecular Formula ]:
C8H15NO3
[ Molecular Weight ]:
173.210
[ Flash Point ]:
104.1±22.6 °C
[ Exact Mass ]:
173.105194
[ PSA ]:
55.40000
[ LogP ]:
1.23
[ Appearance of Characters ]:
Powder | White to yellow
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.436
[ Storage condition ]:
−20°C
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
Xi
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
J. Org. Chem. 63 , 92-98, (1998)
The synthesis of the C(26)-C(32) oxazole fragment 4 and its C(32) epimer 20 of serine/threonine protein phosphatase PP1 and PP2A inhibitor calyculin C is presented. The syn methyl arrangement in 4 was...
Synthesis of a C20-C26 segment of superstolide A by addition of a chiral allenylzinc reagent to (R)-N-boc alaninal.Org. Lett. 7 , 1593-1596, (2005)
[reaction: see text] Additions of chiral allenylzinc and indium reagents to N-Boc alaninal were examined as a possible route to a C20-C26 segment of superstolide A. Allenylzinc reagents, prepared in s...
Practical syntheses of a CXCR3 antagonist.J. Org. Chem. 76 , 1767-1774, (2011)
Two new, reliable syntheses of a pyrido[2,3-d]-pyrimidine inhibitor of the CXCR3 receptor are described. A nine-step synthesis of the CXCR3 inhibitor (1) from 2-aminonicotinic acid was demonstrated on...