3-Bromo-4-methylaniline
Names
[ CAS No. ]:
7745-91-7
[ Name ]:
3-Bromo-4-methylaniline
[Synonym ]:
EINECS 231-807-8
9CI.3-Bromo-p-toluidine
3-Bromo-4-methylaniline
3-Bromo-1,4-toluidine
Benzenamine, 3-bromo-4-methyl-
3-BROMO-PARA-TOLUIDINE
3-bromo-4-methylphenylamine
p-Toluidine,3-bromo
4-AMINO-2-BROMOTOLUENE
3-BROMO-P-TOLUIDINE
3-bromo-4-methyl-aniline
3-bromo-4-methyl-benzenamin
MFCD00134176
3-bromo-p-toluidin
3-bromo-N,N,4-trimethylaniline
Chemical & Physical Properties
[ Density]:
1.5±0.1 g/cm3
[ Boiling Point ]:
258.3±20.0 °C at 760 mmHg
[ Melting Point ]:
27-30 °C(lit.)
[ Molecular Formula ]:
C7H8BrN
[ Molecular Weight ]:
186.049
[ Flash Point ]:
110.0±21.8 °C
[ Exact Mass ]:
184.984009
[ PSA ]:
26.02000
[ LogP ]:
2.56
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.609
[ Storage condition ]:
Refrigerator
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- XU4375000
- CHEMICAL NAME :
- p-Toluidine, 3-bromo-
- CAS REGISTRY NUMBER :
- 7745-91-7
- BEILSTEIN REFERENCE NO. :
- 1562057
- LAST UPDATED :
- 199707
- DATA ITEMS CITED :
- 2
- MOLECULAR FORMULA :
- C7-H8-Br-N
- MOLECULAR WEIGHT :
- 186.07
- WISWESSER LINE NOTATION :
- ZR CE D1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 180 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- ARTODN Archives of Toxicology. (Springer-Verlag, Heidelberger Pl. 3, D-1000 Berlin 33, Fed. Rep. Ger.) V.32- 1974- Volume(issue)/page/year: 54,275,1983
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - wild bird species
- DOSE/DURATION :
- 1900 ug/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 21,315,1972
Safety Information
[ Symbol ]:
GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H301-H315-H319-H335
[ Precautionary Statements ]:
P261-P301 + P310-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
[ Hazard Codes ]:
T:Toxic
[ Risk Phrases ]:
R25;R36/37/38
[ Safety Phrases ]:
S26-S45-S37/39-S28A
[ RIDADR ]:
UN 2811 6.1/PG 3
[ WGK Germany ]:
3
[ RTECS ]:
XU4375000
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1
[ HS Code ]:
2921430090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2921430090
[ Summary ]:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
Articles
Biol. Pharm. Bull. 37(12) , 1907-12, (2014)
TRPV2, a member of the transient receptor potential family, has been isolated as a capsaicin-receptor homolog and is thought to respond to noxious heat. Here we show that TRPV2 mRNA is predominantly e...
Hydroxyl radical formation in the gas phase oxidation of distonic 2-methylphenyl radical cations.Phys. Chem. Chem. Phys. 15(47) , 20577-84, (2013)
The reactions of distonic 4-(N,N,N-trimethylammonium)-2-methylphenyl and 5-(N,N,N-trimethylammonium)-2-methylphenyl radical cations (m/z 149) with O2 are studied in the gas phase using ion-trap mass s...
Formation and stability of gas-phase o-benzoquinone from oxidation of ortho-hydroxyphenyl: a combined neutral and distonic radical study.Phys. Chem. Chem. Phys. 18 , 4320-32, (2016)
Gas-phase product detection studies of o-hydroxyphenyl radical and O2 are reported at 373, 500, and 600 K, at 4 Torr (533.3 Pa), using VUV time-resolved synchrotron photoionisation mass spectrometry. ...