2,2,6,6-Tetramethylpiperidine
Names
[ CAS No. ]:
768-66-1
[ Name ]:
2,2,6,6-Tetramethylpiperidine
[Synonym ]:
Piperidine, 2,2,6,6-tetramethyl-
2,2,6,6-Tetramethylpeperidine
EINECS 212-199-3
2,2,6,6-tetramethyl-piperidine
2,2,6,6-Me4piperidine
2,2,6,6-Tetramethylpiperidine
2,2,6,6-TETRAMETHYL-1-PIPERIDINYLOXY
MFCD00005985
2,2,6,6-tetramethyl piperidine
PIPERIDINE,2,2,6,6-TETRAMETHYL
Norpempidine
Chemical & Physical Properties
[ Density]:
0.8±0.1 g/cm3
[ Boiling Point ]:
157.6±8.0 °C at 760 mmHg
[ Melting Point ]:
-59°C
[ Molecular Formula ]:
C9H19N
[ Molecular Weight ]:
141.254
[ Flash Point ]:
24.4±0.0 °C
[ Exact Mass ]:
141.151749
[ PSA ]:
12.03000
[ LogP ]:
3.00
[ Vapour Pressure ]:
2.7±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.417
[ Storage condition ]:
Flammables area
[ Water Solubility ]:
MISCIBLE
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TN4220000
- CHEMICAL NAME :
- Piperidine, 2,2,6,6-tetramethyl-
- CAS REGISTRY NUMBER :
- 768-66-1
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 3
- MOLECULAR FORMULA :
- C9-H19-N
- MOLECULAR WEIGHT :
- 141.29
- WISWESSER LINE NOTATION :
- T6MTJ B1 B1 F1 F1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 220 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NATUAS Nature. (Nature Subscription Dept., POB 1018, Manasguan, NJ 08736) V.1- 1869- Volume(issue)/page/year: 184,1707,1959
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 33 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NATUAS Nature. (Nature Subscription Dept., POB 1018, Manasguan, NJ 08736) V.1- 1869- Volume(issue)/page/year: 184,1707,1959
Safety Information
[ Symbol ]:
GHS02, GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H226-H301-H315-H319-H335
[ Precautionary Statements ]:
P261-P301 + P310-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xn:Harmful
[ Risk Phrases ]:
R10;R22;R36/37/38
[ Safety Phrases ]:
S26-S37/39-S16
[ RIDADR ]:
UN 1992 3/PG 3
[ WGK Germany ]:
2
[ RTECS ]:
TN4220000
[ Packaging Group ]:
III
[ Hazard Class ]:
3
[ HS Code ]:
29333999
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2933399090
[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
PLoS ONE 10 , e0130442, (2015)
The present study shows the advantages of liposome-based nano-drugs as a novel strategy of delivering active pharmaceutical ingredients for treatment of neurodegenerative diseases that involve neuroin...
Oxidation of primary hydroxyl groups in chitooligomer by a laccase-TEMPO system and physico-chemical characterisation of oxidation products.Carbohydr. Polym. 135 , 234-8, (2015)
The aim of this study was to investigate the oxidation of chitooligomer by a laccase-TEMPO system which had not previously been examined. Chitooligomer was treated with laccase and TEMPO in order to e...
Reactivity of Amine/E(C6F5)3 (E = B, Al) Lewis Pairs toward Linear and Cyclic Acrylic Monomers: Hydrogenation vs. Polymerization.Molecules 20 , 9575-90, (2015)
This work reveals the contrasting reactivity of amine/E(C6F5)3 (E = B, Al) Lewis pairs toward linear and cyclic acrylic monomers, methyl methacrylate (MMA) and biorenewable γ-methyl-α-methylene-γ-buty...